{"id":"W2951118493","doi":"10.1002/chin.200540108","title":"Electronic Nature of N‐Heterocyclic Carbene Ligands: Effect on the Suzuki Reaction.","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Carbene; Combinatorial chemistry; Stereochemistry; Organic chemistry; Medicinal chemistry; Computational chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005935613,0.0004151769,0.0003136987,0.0001800299,0.0003913592,0.0004323052,0.0008643986,0.0004815466,0.009003203],"category_scores_gemma":[0.001143587,0.0002364778,0.0001337293,0.0003077184,0.0004207314,0.0004472852,0.0003322214,0.000604942,0.0008497775],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000381669,"about_ca_system_score_gemma":0.0003766497,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001721912,"about_ca_topic_score_gemma":0.003788823,"domain_scores_codex":[0.9996137,0.0001541302,0.00001246394,0.00005228295,0.00004355583,0.0001237464],"domain_scores_gemma":[0.9993185,0.0004538675,0.00006417491,0.00004242556,0.00004266874,0.0000783686],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.007331126,0.0003264354,0.0005607073,0.0008803448,0.0001583896,0.0004501564,0.000435899,0.001870538,0.9650574,0.00458151,0.002497833,0.0158496],"study_design_scores_gemma":[0.0002669188,0.001576871,0.00146213,0.00009919094,0.00009754944,0.0001932664,0.0002045435,0.002145061,0.9845454,0.0004341565,0.008913429,0.00006163512],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9550661,0.005652341,0.002405309,0.0005519075,0.0001686789,0.00006718279,0.0003318327,0.0001427509,0.03561383],"genre_scores_gemma":[0.9939423,0.002258644,0.0005566155,0.0001348227,0.00002436227,0.00002645574,0.0001936237,0.00003297155,0.00283007],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009003203,"threshold_uncertainty_score":0.0301187,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00363623415325175,"score_gpt":0.2160889037477181,"score_spread":0.2124526695944663,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}