{"id":"W2951171098","doi":"10.1002/chin.200949239","title":"ChemInform Abstract: Asymmetric Hydrogenation, Transfer Hydrogenation and Hydrosilylation of Ketones Catalyzed by Iron Complexes","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Hydrosilylation; Transfer hydrogenation; Catalysis; Combinatorial chemistry; Organic chemistry; Ruthenium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002934081,0.0006617712,0.0003878849,0.0004199605,0.0003304437,0.00034065,0.0006607358,0.0003638122,0.01035573],"category_scores_gemma":[0.0002028415,0.000191759,0.0001972373,0.0003356234,0.0002269471,0.0006183016,0.0003434686,0.0006028831,0.002131587],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005862874,"about_ca_system_score_gemma":0.0004030183,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006813289,"about_ca_topic_score_gemma":0.0009362065,"domain_scores_codex":[0.999836,0.00001432576,0.000009354501,0.00002204444,0.00006112177,0.00005718474],"domain_scores_gemma":[0.9999468,0.000007723587,0.00001136652,0.000006605384,0.000009611987,0.00001786559],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001796593,0.0003902854,0.0005355016,0.001723711,0.0001292969,0.001336027,0.0003388017,0.00249669,0.8719882,0.009076927,0.03659219,0.07359589],"study_design_scores_gemma":[0.000229496,0.0004793457,0.0008466867,0.00003280783,0.00004015247,0.0004065433,0.00003571623,0.002194207,0.9742591,0.0007908517,0.0206597,0.00002531931],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.844355,0.0118741,0.0179376,0.002025686,0.001893265,0.0002537943,0.002137278,0.001441049,0.1180822],"genre_scores_gemma":[0.9641225,0.005107111,0.001994855,0.0001617031,0.0001843714,0.00002312656,0.000930396,0.00009181244,0.02738411],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01035573,"threshold_uncertainty_score":0.03464341,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009036647551601983,"score_gpt":0.2263877305614319,"score_spread":0.2173510830098299,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}