{"id":"W2951186064","doi":"10.1002/chin.200316043","title":"Transition Metal‐Catalyzed Cyclopropanation of Alkenes in Water: Catalyst Efficiency and in situ Generation of the Diazo Reagent.","year":2003,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Cyclopropanation; Diazo; Catalysis; Reagent; In situ; Transition metal; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000162776,0.000340889,0.0001422509,0.0001530017,0.0001361651,0.0002507862,0.0003258012,0.0002376616,0.001958783],"category_scores_gemma":[0.0002376337,0.0001591567,0.00009602583,0.0001298409,0.0001888504,0.0004063222,0.0001855766,0.0003325707,0.0004671445],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002454954,"about_ca_system_score_gemma":0.0001633608,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007760023,"about_ca_topic_score_gemma":0.001496797,"domain_scores_codex":[0.999915,0.00001310585,0.000004401857,0.00002079351,0.00002053388,0.00002618872],"domain_scores_gemma":[0.9999634,0.00001480509,0.000008130089,0.000004135268,0.000005204299,0.000004302747],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0001654574,0.00003337664,0.0001073346,0.0001052519,0.000008907207,0.00006007027,0.00003119584,0.0001732964,0.9917536,0.0005140317,0.0003464923,0.006701144],"study_design_scores_gemma":[0.00001127546,0.00004723391,0.0001393717,0.000002222368,0.000007309102,0.00003444789,0.000007492929,0.0003536285,0.9983089,0.00005362578,0.001032199,0.00000236502],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.9707502,0.004040044,0.007187787,0.0002419343,0.00008236998,0.00004463634,0.0002856956,0.0001480816,0.01721927],"genre_scores_gemma":[0.9954056,0.001160524,0.001018792,0.00001701227,0.000007561621,0.000008590818,0.000115189,0.0000175596,0.002249183],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.001958783,"threshold_uncertainty_score":0.006552815,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01284189978522537,"score_gpt":0.2132484987594862,"score_spread":0.2004065989742609,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}