{"id":"W2951221250","doi":"10.1002/chin.201437065","title":"ChemInform Abstract: α‐Hydroxycyclopentanones via One‐Pot Oxidation of the Trimethylaluminum‐Mediated Nazarov Reaction with Triplet Oxygen.","year":2014,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Oxygen; Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004372872,0.0003277598,0.0004817552,0.0001215932,0.0001424519,0.00003995424,0.0005591984,0.0002878884,0.0008176748],"category_scores_gemma":[0.0005136235,0.0002330609,0.000239732,0.0007345344,0.0001546081,0.0003807151,0.00009976544,0.0002718497,0.00007381701],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001955036,"about_ca_system_score_gemma":0.0001050606,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001316562,"about_ca_topic_score_gemma":0.00001833329,"domain_scores_codex":[0.9978503,3.332216e-7,0.0007399629,0.0003203323,0.0007204838,0.0003685888],"domain_scores_gemma":[0.9976026,0.0003158091,0.0008844048,0.0008872219,0.0001771329,0.0001328118],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001203463,0.0001295047,0.0002502327,0.0001923966,0.0001554547,3.673287e-7,0.0002365506,2.666103e-7,0.3360371,0.00001825373,0.00162803,0.6612315],"study_design_scores_gemma":[0.000908926,0.00002437526,0.003651803,0.00009311675,0.0001651016,0.00001506253,0.0004031542,0.00003729786,0.9547724,0.00002787061,0.03959181,0.0003090561],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.2104362,0.00005442645,0.00000550278,0.0001115677,0.00006604632,0.0001516605,0.00002059572,0.00007713649,0.7890769],"genre_scores_gemma":[0.9826596,0.00004272652,0.00004696309,0.00006835337,0.000182786,0.00005613075,0.0003097721,0.00003882509,0.01659485],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.772482,"threshold_uncertainty_score":0.9503948,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009305619210598049,"score_gpt":0.2010201457680377,"score_spread":0.1917145265574396,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}