{"id":"W2951221250","doi":"10.1002/chin.201437065","title":"ChemInform Abstract: α‐Hydroxycyclopentanones via One‐Pot Oxidation of the Trimethylaluminum‐Mediated Nazarov Reaction with Triplet Oxygen.","year":2014,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Oxygen; Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001320206,0.0005473452,0.0001668231,0.0002571028,0.0002053593,0.0002315583,0.0004245945,0.0002424031,0.004729478],"category_scores_gemma":[0.0001249841,0.0001391707,0.000144554,0.0001840597,0.0001902416,0.0004224622,0.0003095985,0.000548918,0.001364618],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003119989,"about_ca_system_score_gemma":0.0004544372,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003817094,"about_ca_topic_score_gemma":0.0008356925,"domain_scores_codex":[0.9999028,0.00001021807,0.000008138532,0.00002659168,0.00002544906,0.00002668059],"domain_scores_gemma":[0.9999583,0.000004916965,0.00001049989,0.000008471448,0.000007549573,0.00001034918],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002198703,0.0000777497,0.0002195772,0.0003628495,0.00002404811,0.0002964525,0.0001034612,0.0004135654,0.9607348,0.004533995,0.001419407,0.03159425],"study_design_scores_gemma":[0.00003928224,0.0002705903,0.0003589552,0.00001243759,0.00001462934,0.0002457813,0.00001842998,0.0003892652,0.9768044,0.0003351269,0.02150138,0.000009635673],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7649758,0.009974563,0.09732655,0.0009440204,0.001114337,0.0005861411,0.002002412,0.00159911,0.121477],"genre_scores_gemma":[0.9699638,0.002762497,0.01131531,0.0001023899,0.00004412894,0.0001025813,0.0006272253,0.0000976131,0.01498427],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004729478,"threshold_uncertainty_score":0.0158217,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009305619210598049,"score_gpt":0.2010201457680377,"score_spread":0.1917145265574396,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}