{"id":"W2951271370","doi":"10.1002/chin.201330045","title":"ChemInform Abstract: Palladium‐Catalyzed Intermolecular Desulfinylative Cross‐Coupling of Heteroaromatic Sulfinates.","year":2013,"lang":"en","type":"article","venue":"ChemInform","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Concordia University","funders":"","keywords":"Chemistry; Palladium; Intermolecular force; Aryl; Nucleophile; Catalysis; Coupling (piping); Combinatorial chemistry; Coupling reaction; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000243437,0.000644769,0.0001553133,0.0004432466,0.0002745463,0.0002508522,0.0004788477,0.0002917195,0.007709092],"category_scores_gemma":[0.0001337719,0.0002000282,0.0001592332,0.0003141928,0.0002241146,0.0003245435,0.0004035398,0.0005744165,0.003149238],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003817498,"about_ca_system_score_gemma":0.0005849208,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005510816,"about_ca_topic_score_gemma":0.001517221,"domain_scores_codex":[0.9998441,0.00002052716,0.000009020617,0.00003389886,0.0000608835,0.00003147577],"domain_scores_gemma":[0.9999539,0.000005934411,0.00001205576,0.000008028493,0.000009578343,0.00001060697],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003271053,0.0001563417,0.0002786953,0.0005964924,0.00005710999,0.0005123616,0.0002004624,0.001297952,0.9144813,0.01304455,0.01038988,0.05865755],"study_design_scores_gemma":[0.00003788722,0.000218974,0.0004386891,0.00001624643,0.00002511695,0.0003542955,0.00002180651,0.0007280301,0.9424839,0.0005232157,0.05514026,0.00001157063],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5103719,0.01206745,0.1805994,0.002073481,0.000990104,0.0006526051,0.005737465,0.006514931,0.2809926],"genre_scores_gemma":[0.931538,0.00703043,0.02114589,0.0002969764,0.0001053613,0.000104136,0.002419539,0.0001941975,0.03716548],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007709092,"threshold_uncertainty_score":0.02578944,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01432027183656651,"score_gpt":0.2534228625931946,"score_spread":0.2391025907566281,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}