{"id":"W2951278461","doi":"10.1055/s-0034-1380304","title":"Dichlorination of α-Diazo-β-dicarbonyls Using (Dichloroiodo)benzene","year":2015,"lang":"en","type":"article","venue":"Synlett","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada; University of Waterloo","keywords":"Chemistry; Iodobenzene; Diazo; Chemoselectivity; Catalysis; Benzene; Organic chemistry; Halogenation; Lewis acids and bases; Lewis acid catalysis; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002949523,0.000574419,0.0002227001,0.0002394603,0.0001889271,0.0001803971,0.0002457886,0.0001751996,0.001223351],"category_scores_gemma":[0.0002170946,0.0001888812,0.0001565886,0.0002842931,0.0002440563,0.0001673849,0.000209953,0.0004539471,0.0004847932],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003920074,"about_ca_system_score_gemma":0.0002610181,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001093672,"about_ca_topic_score_gemma":0.002295793,"domain_scores_codex":[0.9997672,0.00003385048,0.00001722024,0.00005279266,0.00004488927,0.00008403674],"domain_scores_gemma":[0.9998802,0.00002398728,0.00002635764,0.00001697893,0.00002434254,0.00002817525],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009128546,0.00001011198,0.0001122276,0.00008830283,0.000007566802,0.00008373902,0.00004466869,0.00009372227,0.9975601,0.0002317157,0.00005273724,0.001623627],"study_design_scores_gemma":[0.000009783714,0.0001655674,0.0005499735,0.000005838112,0.000008935484,0.0001068631,0.00001614889,0.0001175373,0.9970058,0.00002923527,0.001980535,0.000003860011],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9747956,0.003098621,0.007167526,0.0001156923,0.00005598196,0.00007589796,0.0003836516,0.0001009727,0.01420586],"genre_scores_gemma":[0.9935471,0.001806219,0.002378753,0.00004384426,0.00001288277,0.00001945897,0.0003015271,0.00002965316,0.001860459],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001223351,"threshold_uncertainty_score":0.004092515,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.07274816434441449,"score_gpt":0.2819134832888772,"score_spread":0.2091653189444627,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}