{"id":"W2951290516","doi":"10.1002/chin.200226074","title":"ChemInform Abstract: A Highly Efficient Strategy for the Synthesis of 3‐Substituted Salicylic Acids by Either Directed ortho‐Lithiation or Halogen—Metal Exchange of Substituted MOM‐Protected Phenols Followed by Carboxylation.","year":2002,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Carboxylation; Halogen; Salicylic acid; Phenols; Combinatorial chemistry; Synthon; Organic chemistry; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001566972,0.0006763009,0.0002300873,0.0003565426,0.0002343138,0.000359276,0.0004437219,0.0002487146,0.006819426],"category_scores_gemma":[0.0001421652,0.0002140395,0.0003189852,0.0003129292,0.0001711051,0.0004701391,0.0004183739,0.0005043239,0.004491782],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003061444,"about_ca_system_score_gemma":0.0006366218,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005554085,"about_ca_topic_score_gemma":0.0009698772,"domain_scores_codex":[0.9998633,0.00001821751,0.0000108597,0.00002386125,0.00004970144,0.00003414506],"domain_scores_gemma":[0.9999501,0.000005271202,0.00001143689,0.000009807133,0.000007758696,0.00001566351],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002957856,0.00005689974,0.0001434643,0.0005409325,0.00003449124,0.0002701472,0.00006643707,0.0005022724,0.950104,0.0020367,0.003787281,0.04216139],"study_design_scores_gemma":[0.00003634266,0.0001735869,0.0004373049,0.00001124857,0.00001987347,0.0003127946,0.00001043206,0.000432314,0.9738303,0.0002966856,0.02442535,0.00001378303],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6611286,0.01827285,0.1827319,0.001503381,0.001345794,0.0006265381,0.01083991,0.005772732,0.1177783],"genre_scores_gemma":[0.9143733,0.008696616,0.03681743,0.0003404983,0.0001180958,0.0001034468,0.004433056,0.0005046657,0.03461289],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006819426,"threshold_uncertainty_score":0.02281326,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02503701111752767,"score_gpt":0.2342537753641324,"score_spread":0.2092167642466047,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}