{"id":"W2951308007","doi":"10.1080/10426500212298","title":"P(RNCH 2 CH 2 ) 3 N as Very Strong Non-Ionic Bases and Catalysts: Recent Advances and Applications","year":2002,"lang":"en","type":"article","venue":"Phosphorus, sulfur, and silicon and the related elements","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"University of Regina; American Chemical Society Petroleum Research Fund; National Science Foundation","keywords":"Catalysis; Stoichiometry; Ionic bonding; Chemistry; Fluorine; Lewis acids and bases; Combinatorial chemistry; Organic chemistry; Ion","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003022363,0.0002651294,0.0001882,0.0002893018,0.0001115498,0.0003584185,0.0003739209,0.0003660474,0.001528234],"category_scores_gemma":[0.000165759,0.0001322161,0.00008682765,0.0002736358,0.0003365305,0.0004099716,0.0003462333,0.0003541466,0.0006473899],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001986871,"about_ca_system_score_gemma":0.0001172511,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002171751,"about_ca_topic_score_gemma":0.0003894189,"domain_scores_codex":[0.9998807,0.00002648368,0.000007392831,0.0000206348,0.00005082141,0.00001402328],"domain_scores_gemma":[0.9999388,0.00002486076,0.0000101491,0.000006197482,0.000009337014,0.00001061513],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003599624,0.0000831716,0.0005612175,0.001306928,0.00002939591,0.0003069264,0.0001007678,0.001370963,0.8332047,0.0143522,0.001161556,0.1471622],"study_design_scores_gemma":[0.00008751619,0.000811914,0.001250056,0.00005453493,0.00003983952,0.001034393,0.00006734557,0.002379047,0.8803537,0.004476157,0.1094179,0.00002755506],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6796436,0.2279017,0.02572799,0.00112471,0.0003630191,0.00009145821,0.0002073948,0.0004274153,0.06451271],"genre_scores_gemma":[0.929905,0.05186892,0.008956955,0.0002627502,0.0002100098,0.0000388703,0.0001754639,0.00003241861,0.008549672],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001528234,"threshold_uncertainty_score":0.005112469,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006666465997941264,"score_gpt":0.2248431899601848,"score_spread":0.2181767239622436,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}