{"id":"W2951329908","doi":"10.1021/ol0710818","title":"Efficient Nucleophilic Aromatic Substitution between Aryl Nitrofluorides and Alkynes","year":2007,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"Boehringer Ingelheim (Canada)","funders":"","keywords":"Chemistry; Aryl; Nucleophilic aromatic substitution; Trimethylsilyl; Nucleophilic substitution; Amide; Medicinal chemistry; Nucleophile; Base (topology); Radical-nucleophilic aromatic substitution; Substitution reaction; Electrophilic aromatic substitution; Substitution (logic); Organic chemistry; Combinatorial chemistry; Catalysis; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002152116,0.0001766335,0.0001856179,0.00008302246,0.0002093988,0.00007531275,0.0001353938,0.00009108552,0.0001737502],"category_scores_gemma":[0.0001215072,0.0001812361,0.00005616721,0.000192203,0.0001981499,0.00005487605,0.0000555395,0.0002091655,0.0001554855],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002188632,"about_ca_system_score_gemma":0.00002600317,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005997817,"about_ca_topic_score_gemma":0.00001159805,"domain_scores_codex":[0.9988461,4.780173e-7,0.0002851314,0.0003049205,0.000221775,0.0003416295],"domain_scores_gemma":[0.9991962,0.0002206533,0.0000981724,0.0003466402,0.0000169614,0.000121381],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000005909541,0.00002834588,0.01397071,0.00005084681,0.000036505,0.00001807177,0.0002260812,0.00001512648,0.9850855,0.00003926296,0.0001213533,0.0004022871],"study_design_scores_gemma":[0.0004898149,0.000005768959,0.04150656,0.00005738537,0.0001050155,0.00007728924,0.0001735605,0.0001371268,0.9568553,0.00008613052,0.0002405407,0.0002655222],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979981,0.0000672251,0.0005381777,0.0009093675,0.0001345871,0.00006630852,0.000009479833,0.0001993216,0.00007740678],"genre_scores_gemma":[0.9992999,0.000003441311,0.00004038354,0.000179964,0.0003708366,0.000002709337,0.00003371354,0.00003415517,0.00003486219],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02823021,"threshold_uncertainty_score":0.7390594,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009647561178209033,"score_gpt":0.2338836896522666,"score_spread":0.2242361284740575,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}