{"id":"W2951329908","doi":"10.1021/ol0710818","title":"Efficient Nucleophilic Aromatic Substitution between Aryl Nitrofluorides and Alkynes","year":2007,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"Boehringer Ingelheim (Canada)","funders":"","keywords":"Chemistry; Aryl; Nucleophilic aromatic substitution; Trimethylsilyl; Nucleophilic substitution; Amide; Medicinal chemistry; Nucleophile; Base (topology); Radical-nucleophilic aromatic substitution; Substitution reaction; Electrophilic aromatic substitution; Substitution (logic); Organic chemistry; Combinatorial chemistry; Catalysis; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000294669,0.0006693722,0.0004135808,0.0001864843,0.0002328371,0.0002065213,0.0004165983,0.000302987,0.001471831],"category_scores_gemma":[0.0001953639,0.0002046261,0.0001950795,0.000195385,0.0002314533,0.000295154,0.0003921016,0.0002811133,0.0005340243],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000270408,"about_ca_system_score_gemma":0.000272097,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001025038,"about_ca_topic_score_gemma":0.003057291,"domain_scores_codex":[0.9997879,0.00003550765,0.00001288346,0.0000318981,0.00004881925,0.00008306105],"domain_scores_gemma":[0.9999294,0.00001430073,0.00002016628,0.00001205169,0.00000802111,0.00001613202],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001413698,0.0000228275,0.0001400479,0.000092134,0.00001133383,0.000248092,0.00005295025,0.0002084022,0.9942122,0.000655798,0.0001146764,0.004100038],"study_design_scores_gemma":[0.00002015758,0.00016878,0.0004973727,0.000006304155,0.00000947322,0.000286817,0.0000112631,0.000267044,0.9960775,0.00004726192,0.002600421,0.00000763519],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9841882,0.002206531,0.006339019,0.00008134963,0.00004677388,0.00004931649,0.0002261357,0.0001355968,0.00672699],"genre_scores_gemma":[0.9918295,0.001862424,0.003347526,0.00001928865,0.00001436617,0.00002080383,0.0001681583,0.00003032918,0.002707633],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001471831,"threshold_uncertainty_score":0.004923701,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009647561178209033,"score_gpt":0.2338836896522666,"score_spread":0.2242361284740575,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}