{"id":"W2951343765","doi":"10.1021/ic302468j","title":"Crystal Structures and Raman Spectra of Imidazolium Poly[perfluorotitanate(IV)] Salts Containing the [TiF<sub>6</sub>]<sup>2–</sup>, ([Ti<sub>2</sub>F<sub>9</sub>]<sup>−</sup>)<sub><i>∞</i></sub>, and [Ti<sub>2</sub>F<sub>11</sub>]<sup>3–</sup> and the New [Ti<sub>4</sub>F<sub>20</sub>]<sup>4–</sup> and [Ti<sub>5</sub>F<sub>23</sub>]<sup>3–</sup> Anions","year":2013,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Octahedron; Crystallography; Crystal structure; Hydrogen bond; Molecule; Imidazole; Raman spectroscopy; Salt (chemistry); Ring (chemistry); Stereochemistry; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","metaepi_broad","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","open_science","research_integrity"],"category_scores_codex":[0.007743475,0.01742708,0.01511923,0.003846291,0.01022215,0.007923349,0.01163842,0.01368074,0.0004826728],"category_scores_gemma":[0.004608194,0.01694213,0.006180599,0.009933604,0.01307987,0.007077564,0.01008156,0.02119672,0.001318239],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.006321062,"about_ca_system_score_gemma":0.007406527,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009284514,"about_ca_topic_score_gemma":0.001044714,"domain_scores_codex":[0.935069,0.003770993,0.01598569,0.01709686,0.01082233,0.0172551],"domain_scores_gemma":[0.9534271,0.007703938,0.009132163,0.01444821,0.004956298,0.01033225],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.004965489,0.002845817,0.002659437,0.005365462,0.007922188,0.002064304,0.01339808,0.005693878,0.9078478,0.0008366348,0.02327857,0.02312232],"study_design_scores_gemma":[0.0298177,0.001728362,0.001651813,0.004572015,0.00743061,0.01084046,0.01574385,0.0213307,0.8845638,0.004680496,0.00176222,0.015878],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.949167,0.02204656,0.000481986,0.004307966,0.002292009,0.01022887,0.00519543,0.00451726,0.001762924],"genre_scores_gemma":[0.9446459,0.02929198,0.000378219,0.003164568,0.01004841,0.002152407,0.004983861,0.005183227,0.0001513714],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02485222,"threshold_uncertainty_score":0.9995024,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005071558123200533,"score_gpt":0.1886305457911499,"score_spread":0.1835589876679493,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}