{"id":"W2951360474","doi":"10.1002/chin.200745164","title":"Synthesis of Large Ring Macrocycles (12‐18) by Recyclable Palladium‐Complexed Dendrimers on Silica Gel Catalyzed Intramolecular Cyclocarbonylation Reactions.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Dendrimers and Hyperbranched Polymers","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Intramolecular force; Catalysis; Ring (chemistry); Dendrimer; Palladium; Silica gel; Click chemistry; Polymer chemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001291235,0.0004379387,0.0002352489,0.00027536,0.0001675259,0.0003144718,0.0003026919,0.0002184232,0.004276435],"category_scores_gemma":[0.0001569467,0.0002597769,0.0002090216,0.0002174926,0.0001841357,0.0004326765,0.000351944,0.0003900336,0.002130653],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003650995,"about_ca_system_score_gemma":0.0003437582,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003728989,"about_ca_topic_score_gemma":0.001297312,"domain_scores_codex":[0.999928,0.000005725798,0.000006564716,0.00002207849,0.00001259793,0.00002500628],"domain_scores_gemma":[0.9999384,0.000008344329,0.00001874182,0.000006916992,0.000005660018,0.00002204922],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001361534,0.0000413116,0.0000823736,0.0002444379,0.00001566477,0.0001937545,0.0000715948,0.0005022566,0.9763125,0.00139418,0.001058769,0.01994695],"study_design_scores_gemma":[0.00005080072,0.0003551535,0.0007254085,0.00002234574,0.00002087436,0.0001800542,0.00001268311,0.0004431051,0.9731836,0.0002523302,0.02473043,0.00002312593],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9013435,0.01210652,0.04025538,0.0004692966,0.0004996968,0.0006688733,0.003538076,0.001869839,0.03924883],"genre_scores_gemma":[0.9340517,0.008046332,0.03322154,0.0001725672,0.00007286016,0.000330618,0.001145364,0.0002913887,0.02266768],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004276435,"threshold_uncertainty_score":0.01430607,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0116813397842288,"score_gpt":0.2485228422249992,"score_spread":0.2368415024407703,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}