{"id":"W2951362576","doi":"10.1002/chin.201348089","title":"ChemInform Abstract: Addressing Challenges in Palladium‐Catalyzed Cross‐Couplings of Aryl Mesylates: Monoarylation of Ketones and Primary Alkyl Amines.","year":2013,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"","keywords":"Chemistry; Aryl; Amination; Alkyl; Primary (astronomy); Mesylate; Catalysis; Palladium; Phenol; Organic chemistry; Combinatorial chemistry; Coupling (piping)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008666649,0.0009331809,0.0003161025,0.0004436226,0.000425319,0.001014259,0.000809241,0.0008222167,0.01033752],"category_scores_gemma":[0.0005487616,0.0003801338,0.0001961578,0.000502314,0.0003642064,0.001116277,0.0006987279,0.001655361,0.008166485],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006039413,"about_ca_system_score_gemma":0.0009330195,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008333526,"about_ca_topic_score_gemma":0.002111483,"domain_scores_codex":[0.9996666,0.00005643172,0.00002118449,0.00005340643,0.0001519983,0.00005049817],"domain_scores_gemma":[0.9998372,0.0000366549,0.00003140883,0.00002209076,0.00004830296,0.00002434163],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006017739,0.000249341,0.0006161744,0.002399927,0.0001011803,0.0008426452,0.0002913115,0.00166915,0.6965814,0.02876232,0.03454168,0.2333432],"study_design_scores_gemma":[0.00006696569,0.0003584143,0.0005902143,0.0001117994,0.00007588257,0.001178288,0.00009788601,0.001327217,0.7666548,0.002453316,0.2270544,0.00003068709],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.2712991,0.09024787,0.2348084,0.01141836,0.002227728,0.0006124813,0.004482159,0.007623137,0.3772808],"genre_scores_gemma":[0.7787632,0.07241783,0.07341967,0.002464058,0.0004939151,0.0002486347,0.005439733,0.0005180743,0.06623501],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.01033752,"threshold_uncertainty_score":0.0345825,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03581813407011493,"score_gpt":0.2764177675301258,"score_spread":0.2405996334600109,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}