{"id":"W2951363874","doi":"10.1002/chin.200825164","title":"ChemInform Abstract: Synthesis of 3‐Substituted‐3,4‐dihydro‐2H‐1,3‐benzothiazin‐2‐ones via a Highly Regioselective Palladium‐Catalyzed Carbonylation of 2‐Substituted‐2,3‐dihydro‐1,2‐benzisothiazoles.","year":2008,"lang":"en","type":"article","venue":"ChemInform","topic":"Phenothiazines and Benzothiazines Synthesis and Activities","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Regioselectivity; Carbonylation; Palladium; Catalysis; Combinatorial chemistry; Organic chemistry; Carbon monoxide","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003280765,0.0007405244,0.001062421,0.0002801988,0.0002501587,0.00003092759,0.0006972423,0.0006800984,0.0001840314],"category_scores_gemma":[0.0004299521,0.0006922465,0.0005857433,0.0005203924,0.0007402303,0.0001157769,0.0002082598,0.0003010811,0.00001897887],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009940619,"about_ca_system_score_gemma":0.0004300393,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004321684,"about_ca_topic_score_gemma":0.0001037086,"domain_scores_codex":[0.9965478,0.000001902086,0.001351712,0.0006952413,0.0006623589,0.0007409563],"domain_scores_gemma":[0.996905,0.0001546458,0.001146373,0.001004689,0.000538741,0.0002505788],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005489507,0.0004378641,0.0006073948,0.00059283,0.000476651,0.00001284046,0.000919561,0.00003666832,0.9585161,0.0002775243,0.003057364,0.03451621],"study_design_scores_gemma":[0.0009093907,0.0000969481,0.00358256,0.0002136491,0.0001527431,0.0001000717,0.0002457594,0.00008163422,0.9836882,0.00009362926,0.01005178,0.0007836032],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8327841,0.001550821,0.00002645795,0.000107201,0.0003451217,0.0005566326,0.0001942286,0.00008540355,0.1643501],"genre_scores_gemma":[0.9957911,0.001185079,0.0001770231,0.00006307004,0.000492359,0.0001094149,0.000346308,0.00008429488,0.001751367],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.163007,"threshold_uncertainty_score":0.9995528,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01249219834810638,"score_gpt":0.2150946646796112,"score_spread":0.2026024663315048,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}