{"id":"W2951363874","doi":"10.1002/chin.200825164","title":"ChemInform Abstract: Synthesis of 3‐Substituted‐3,4‐dihydro‐2H‐1,3‐benzothiazin‐2‐ones via a Highly Regioselective Palladium‐Catalyzed Carbonylation of 2‐Substituted‐2,3‐dihydro‐1,2‐benzisothiazoles.","year":2008,"lang":"en","type":"article","venue":"ChemInform","topic":"Phenothiazines and Benzothiazines Synthesis and Activities","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Regioselectivity; Carbonylation; Palladium; Catalysis; Combinatorial chemistry; Organic chemistry; Carbon monoxide","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001164889,0.0006869668,0.0002957783,0.00035061,0.0002455471,0.0002328968,0.0006449801,0.0003114316,0.007622569],"category_scores_gemma":[0.0001262924,0.0002527122,0.0002390337,0.0004221403,0.0002001964,0.0003096121,0.000322649,0.0005771195,0.00300137],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005323049,"about_ca_system_score_gemma":0.0008617411,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001558686,"about_ca_topic_score_gemma":0.003188257,"domain_scores_codex":[0.9999231,0.000009120961,0.000004659144,0.00001431839,0.0000220369,0.00002677703],"domain_scores_gemma":[0.9999512,0.000004792172,0.00001100563,0.000005955497,0.000009048924,0.00001796349],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000380136,0.0001397151,0.0001771764,0.0009051219,0.00005239667,0.0006514249,0.000145498,0.001293711,0.9611214,0.002103448,0.006883907,0.02614605],"study_design_scores_gemma":[0.0001655459,0.0009452947,0.001885832,0.00002465979,0.00004840971,0.0006601962,0.00002472917,0.001006004,0.9600558,0.000370528,0.03477811,0.00003494727],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7664067,0.02048383,0.07669766,0.001907955,0.001272754,0.001095504,0.01806405,0.003804317,0.1102673],"genre_scores_gemma":[0.9246302,0.012903,0.01459375,0.0003619401,0.0001352827,0.0002128852,0.005727159,0.0002109563,0.04122501],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007622569,"threshold_uncertainty_score":0.02550006,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01249219834810638,"score_gpt":0.2150946646796112,"score_spread":0.2026024663315048,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}