{"id":"W2951366110","doi":"10.1021/ol7022054","title":"Rh(I)-Catalyzed Carbonylative Ring Opening of Diazabicycles with Acyl Anion Equivalents","year":2007,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":46,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Deutscher Akademischer Austauschdienst","keywords":"Chemistry; Desymmetrization; Cyclopentene; Nucleophile; Catalysis; Ring (chemistry); Ion; Medicinal chemistry; Combinatorial chemistry; Organic chemistry; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001901341,0.0005997913,0.0003205928,0.0001713982,0.0001756541,0.0002389451,0.0004447013,0.0002408361,0.001621254],"category_scores_gemma":[0.0001287446,0.0001854887,0.0002124396,0.0001197337,0.0002715737,0.0002604091,0.0003614425,0.0005690736,0.0008491664],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002822307,"about_ca_system_score_gemma":0.000240121,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003983653,"about_ca_topic_score_gemma":0.0008454086,"domain_scores_codex":[0.9998393,0.00001989255,0.00001169423,0.00003615746,0.00003808209,0.0000548528],"domain_scores_gemma":[0.9999192,0.00001163071,0.00002229162,0.00001122362,0.000008529574,0.00002706898],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000076308,0.00002032873,0.00007482729,0.00007246639,0.000005797055,0.0002027368,0.00004774395,0.0001196371,0.9954093,0.0007868026,0.0001374675,0.003046636],"study_design_scores_gemma":[0.00001033393,0.00009961907,0.0002118572,0.000002833443,0.000007034601,0.0002050095,0.000007927512,0.0001798686,0.9959126,0.00005730574,0.003298493,0.000007121902],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9501472,0.002737508,0.02281536,0.00025539,0.0001749118,0.0001283246,0.0006499671,0.0005905933,0.02250077],"genre_scores_gemma":[0.9835444,0.001789658,0.008619913,0.00005324538,0.00003622974,0.00007177149,0.0004244256,0.00006452726,0.005395737],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001621254,"threshold_uncertainty_score":0.005423605,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01567260497304304,"score_gpt":0.2651446273244318,"score_spread":0.2494720223513887,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}