{"id":"W2951409706","doi":"10.1021/ja010262g","title":"Effects of Halide Ligands and Protic Additives on Enantioselectivity and Reactivity in Rhodium-Catalyzed Asymmetric Ring-Opening Reactions","year":2001,"lang":"en","type":"letter","venue":"Journal of the American Chemical Society","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":120,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Reactivity (psychology); Rhodium; Halide; Chemistry; Citation; Ring (chemistry); Library science; Medicinal chemistry; Computer science; Catalysis; Organic chemistry; Medicine","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["research_integrity"],"consensus_categories":[],"category_scores_codex":[0.0004679865,0.0003237987,0.0009917661,0.0002109501,0.00009649065,0.0000417404,0.0003385733,0.0003234471,0.000009574447],"category_scores_gemma":[0.001676665,0.0002365759,0.0005751498,0.001578399,0.0004669249,0.0001387785,0.0001607414,0.002629365,4.997928e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003700266,"about_ca_system_score_gemma":0.000112463,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001687845,"about_ca_topic_score_gemma":0.000001293801,"domain_scores_codex":[0.9979819,0.00009789165,0.0006200306,0.0003532286,0.000630574,0.0003163735],"domain_scores_gemma":[0.9952919,0.002090194,0.002120453,0.0002689357,0.0001314418,0.00009707747],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001373068,0.0004385884,0.004466368,0.000905755,0.0008995978,0.00006657936,0.0003774053,0.00000485335,0.9533752,0.000002094248,0.02065766,0.01866855],"study_design_scores_gemma":[0.001111391,0.00006322122,0.004645932,0.0006354928,0.000439199,0.0002173267,0.0001504107,0.0001180644,0.9843515,0.00006134973,0.007861513,0.0003446238],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9853867,0.0002567791,0.00004506477,0.01356646,0.00004304892,0.0001398762,0.0000221009,0.00001315393,0.0005268404],"genre_scores_gemma":[0.9930356,0.0007541536,0.0002137679,0.005193998,0.0005540321,0.00001570979,0.00001231646,0.0000403233,0.0001800547],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03097624,"threshold_uncertainty_score":0.9996716,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0073886077184953,"score_gpt":0.2372085923111486,"score_spread":0.2298199845926533,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}