{"id":"W2951417569","doi":"10.1021/ol802142k","title":"Chemoselective Oxygen-Centered Radical Cyclizations onto Silyl Enol Ethers","year":2008,"lang":"en","type":"article","venue":"Organic Letters","topic":"Traditional and Medicinal Uses of Annonaceae","field":"Biochemistry, Genetics and Molecular Biology","cited_by":54,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Silylation; Enol; Oxygen; Organic chemistry; Photochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004146283,0.0001415623,0.0001163249,0.00002526507,0.0001433546,0.000006842896,0.0001639219,0.0000940099,0.0001303859],"category_scores_gemma":[0.00005628081,0.0001339755,0.00007897021,0.00008487671,0.0001804037,0.000005789083,0.00003267467,0.0001197958,0.00008042485],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004348802,"about_ca_system_score_gemma":0.00009954403,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001981,"about_ca_topic_score_gemma":0.00001698915,"domain_scores_codex":[0.999136,0.00003036554,0.0001390909,0.0002878529,0.0001663889,0.0002402633],"domain_scores_gemma":[0.9995913,0.0000119985,0.00004459181,0.0001849407,0.0000409986,0.0001261656],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004574532,0.00007945583,0.000479774,0.00000447445,0.00006818648,0.00001981055,0.0001749365,0.000006705322,0.9219309,0.00003215265,0.07707008,0.00008774216],"study_design_scores_gemma":[0.001907631,0.0003099393,0.01715438,0.00002270888,0.00004245669,0.0004292518,0.00007417078,0.00001120291,0.7032911,0.00003951586,0.2763001,0.0004174838],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9915689,0.0002895543,0.001702913,0.005412864,0.0001709579,0.0001283504,0.00001716657,0.00003153189,0.0006777202],"genre_scores_gemma":[0.9882892,0.0002227311,0.0003382092,0.01005452,0.000503398,0.00001053615,0.0002139843,0.00002943247,0.0003380344],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2186398,"threshold_uncertainty_score":0.5463362,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01274722346350566,"score_gpt":0.2194882709505939,"score_spread":0.2067410474870883,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}