{"id":"W2951430065","doi":"10.1002/chin.201029057","title":"ChemInform Abstract: Intramolecular Simmons—Smith Cyclopropanation. Studies into the Reactivity of Alkyl‐Substituted Zinc Carbenoids, Effect of Directing Groups and Synthesis of Bicyclo[n.1.0]alkanes.","year":2010,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Cyclopropanation; Intramolecular force; Reactivity (psychology); Alkyl; Bicyclic molecule; Zinc; Medicinal chemistry; Stereochemistry; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0007621165,0.0004401729,0.0008919702,0.0001421662,0.0001503997,0.00002237347,0.0004169035,0.0003322532,0.0001226288],"category_scores_gemma":[0.002665243,0.0003254467,0.0002291815,0.0003579553,0.0006180085,0.0003305867,0.0002338168,0.0006156071,0.000002116994],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001101215,"about_ca_system_score_gemma":0.0001190188,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003339276,"about_ca_topic_score_gemma":0.000154971,"domain_scores_codex":[0.9977578,9.895748e-7,0.0009403459,0.0003610193,0.0006015803,0.0003382965],"domain_scores_gemma":[0.9961456,0.001356236,0.001161373,0.0008073455,0.0004188808,0.0001105731],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009516558,0.00005405642,0.0003019084,0.002412544,0.0002341469,0.000002951173,0.001904259,6.912109e-7,0.6492718,0.00006812673,0.00002685353,0.3456275],"study_design_scores_gemma":[0.0005893838,0.00003749482,0.0007610812,0.0002945726,0.00030713,0.00003789053,0.002454946,0.00001999643,0.9938765,0.00006875954,0.001254831,0.0002974336],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8940182,0.0009156597,6.436636e-7,0.00002993972,0.0001390373,0.0002853857,0.00002729099,0.00007559214,0.1045082],"genre_scores_gemma":[0.9989933,0.0004138897,0.0001392734,0.000004133484,0.00009238317,0.00009464586,0.00002703273,0.00004355868,0.0001917547],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.34533,"threshold_uncertainty_score":0.9999198,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007008580779217705,"score_gpt":0.2405381559672382,"score_spread":0.2335295751880205,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}