{"id":"W2951443000","doi":"10.1002/chin.200433117","title":"Regiospecific Synthesis of Alkylphenanthrenes Using a Combined Directed ortho and Remote Metalation‐Suzuki—Miyaura Cross Coupling Strategy.","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Metalation; Combinatorial chemistry; Coupling (piping); Coupling reaction; Organic chemistry; Stereochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001689484,0.0002980448,0.0004561532,0.0000893675,0.0002610385,0.0001570323,0.000198228,0.0002233683,0.0001723517],"category_scores_gemma":[0.0003505467,0.0003013013,0.000156507,0.0003411358,0.0004200122,0.0003469369,0.00009330039,0.0002140061,0.000007180718],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002525765,"about_ca_system_score_gemma":0.0002137197,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000524043,"about_ca_topic_score_gemma":0.00005444753,"domain_scores_codex":[0.9983022,2.689688e-8,0.0006674993,0.0003668354,0.0003071752,0.0003562676],"domain_scores_gemma":[0.998359,0.0002335283,0.0004317192,0.0005900391,0.0002515691,0.0001341954],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002143406,0.0001465914,0.001881195,0.0007449802,0.0002786951,0.00001865584,0.0004928795,0.002141652,0.9746234,0.0004535108,0.00002659632,0.01897748],"study_design_scores_gemma":[0.0008906503,0.00001090016,0.001680376,0.0003728395,0.0001404413,0.00007803772,0.0003991893,0.005547047,0.9901323,0.0003193512,0.00009398401,0.0003349392],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9907562,0.0002706341,0.00001312766,0.00002519214,0.00006423891,0.000108929,0.00005229574,0.0002350226,0.008474398],"genre_scores_gemma":[0.9985711,0.00008459514,0.0002872201,0.000003679481,0.00006942663,0.000007432665,0.00006118001,0.00004880916,0.0008665483],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01864254,"threshold_uncertainty_score":0.9999439,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02733811709670335,"score_gpt":0.2861360952855155,"score_spread":0.2587979781888121,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}