{"id":"W2951469517","doi":"10.1021/ol017104e","title":"Palladium(II)-Catalyzed Transfer Vinylation of Protected Monosaccharides","year":2002,"lang":"en","type":"article","venue":"Organic Letters","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":62,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Monosaccharide; Catalysis; Anomer; Yield (engineering); Palladium; Organic chemistry; Decomposition; Ligand (biochemistry); Solvent; Ether; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005062939,0.0001692204,0.0002117631,0.00003448297,0.00008374456,0.00001662875,0.0001991486,0.0001223152,0.01195072],"category_scores_gemma":[0.00006266983,0.0001698534,0.0001061996,0.0001824454,0.00006212483,0.0000889005,0.0000243365,0.0001481728,0.00004291545],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000665775,"about_ca_system_score_gemma":0.00000992177,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002201543,"about_ca_topic_score_gemma":0.00000311139,"domain_scores_codex":[0.9990474,0.00001082026,0.0002874983,0.0002556283,0.0001863957,0.0002122803],"domain_scores_gemma":[0.9994446,0.00004829272,0.00005829839,0.0003571711,0.00003043957,0.00006122185],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001530166,0.00006398104,0.000155195,0.0001125608,0.00005321447,0.000006498711,0.0007532374,0.00000426592,0.9978846,0.000004100263,0.0003350962,0.0006120064],"study_design_scores_gemma":[0.0003944105,0.000004683702,0.00006856766,0.00003944177,0.00004368762,0.000007795695,0.00005213491,0.000231229,0.9986884,0.000009637821,0.0002724266,0.0001875692],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964768,0.00005454833,0.0001573986,0.001725922,0.00003081253,0.00007054177,0.00001665494,0.0001012125,0.001366101],"genre_scores_gemma":[0.9994069,0.0000190052,0.00006688212,0.0001166042,0.0001176247,0.00001750018,0.0000221982,0.0000303987,0.0002029192],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01190781,"threshold_uncertainty_score":0.9889525,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0134808408972975,"score_gpt":0.1838045842097344,"score_spread":0.1703237433124369,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}