{"id":"W2951469517","doi":"10.1021/ol017104e","title":"Palladium(II)-Catalyzed Transfer Vinylation of Protected Monosaccharides","year":2002,"lang":"en","type":"article","venue":"Organic Letters","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":62,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Monosaccharide; Catalysis; Anomer; Yield (engineering); Palladium; Organic chemistry; Decomposition; Ligand (biochemistry); Solvent; Ether; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009929343,0.0005643723,0.0002980127,0.0002046136,0.0001518163,0.0003651386,0.0004647525,0.0002329734,0.001351349],"category_scores_gemma":[0.0001304925,0.0001976583,0.0002421719,0.0002221444,0.0001828738,0.0003384592,0.0002914153,0.0006382132,0.0006566403],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003299167,"about_ca_system_score_gemma":0.000293826,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004405529,"about_ca_topic_score_gemma":0.0007261519,"domain_scores_codex":[0.9999032,0.000009533604,0.000006366833,0.00002345943,0.00002828134,0.00002921289],"domain_scores_gemma":[0.999957,0.000004279401,0.000010997,0.000006122388,0.000005270811,0.00001647335],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006514982,0.00002570375,0.00007570785,0.0000999457,0.00001449945,0.0001551637,0.00002162966,0.0003337445,0.986134,0.000712069,0.0001553781,0.01220703],"study_design_scores_gemma":[0.000005728604,0.00005163568,0.0001486598,0.000001509927,0.000006479218,0.0001568464,0.000005105301,0.0002625592,0.9965833,0.00008210696,0.002692467,0.000003611842],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8018676,0.008057022,0.1740211,0.0003123753,0.0003050771,0.0002133842,0.0008371196,0.001041197,0.01334509],"genre_scores_gemma":[0.9569217,0.004063654,0.02593873,0.0000611975,0.00002312557,0.0000401993,0.0007788978,0.00008018806,0.01209234],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001351349,"threshold_uncertainty_score":0.004520714,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0134808408972975,"score_gpt":0.1838045842097344,"score_spread":0.1703237433124369,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}