{"id":"W2951498451","doi":"10.1021/ol800307g","title":"Anionic Indole <i>N</i>-Carbamoyl N → C Translocation. A Directed remote Metalation Route to 2-Aryl- and 2-Heteroarylindoles. Synthesis of Benz[<i>a</i>]carbazoles and Indeno[1,2-<i>b</i>]indoles","year":2008,"lang":"en","type":"article","venue":"Organic Letters","topic":"Coordination Chemistry and Organometallics","field":"Chemistry","cited_by":51,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Universities Space Research Association","keywords":"Chemistry; Aryl; Indole test; Combinatorial chemistry; Metalation; Stereochemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000133989,0.0003899598,0.0001613437,0.0001305011,0.0002118413,0.0001682823,0.0004912407,0.0002320454,0.001886695],"category_scores_gemma":[0.00009804357,0.0001484399,0.000177669,0.0001056651,0.00019571,0.0002166601,0.0003049428,0.000405843,0.0006343799],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003501714,"about_ca_system_score_gemma":0.0002480874,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008097131,"about_ca_topic_score_gemma":0.002125628,"domain_scores_codex":[0.9998643,0.00001910488,0.000008447025,0.00003401366,0.00002741536,0.00004663011],"domain_scores_gemma":[0.9999427,0.000006075496,0.00001856455,0.00001051716,0.000008400062,0.00001382732],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007796937,0.00002724456,0.00006658868,0.000083226,0.000004718146,0.0001220469,0.00004365822,0.00008533863,0.995577,0.0009371851,0.0002240234,0.002750908],"study_design_scores_gemma":[0.00003490239,0.00019151,0.0006876861,0.00000628284,0.000008235444,0.0003222159,0.00001779348,0.0003935331,0.9911544,0.0001191356,0.007052454,0.00001181604],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9378381,0.00291932,0.03068161,0.0003144824,0.0001326209,0.0002220522,0.000611858,0.0008254045,0.02645463],"genre_scores_gemma":[0.9846597,0.0008845774,0.007250695,0.0000867725,0.00001128939,0.00007320942,0.0002890536,0.00003966995,0.006705103],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001886695,"threshold_uncertainty_score":0.006311655,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009988951669830765,"score_gpt":0.1987012276523687,"score_spread":0.188712275982538,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}