{"id":"W2951565628","doi":"10.1002/chin.200935096","title":"ChemInform Abstract: Cross‐Coupling Reactions of Chiral Secondary Organoboronic Esters with Retention of Configuration.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Axial and Atropisomeric Chirality Synthesis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Coupling (piping); Combinatorial chemistry; Service (business); Business; Mechanical engineering; Marketing","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00009051558,0.0002069708,0.0003257613,0.00004562603,0.00008452341,0.0000279312,0.0001984513,0.0001561345,0.003017014],"category_scores_gemma":[0.00005984866,0.0001803671,0.0001473487,0.0001587751,0.0001805741,0.0004750874,0.00002068686,0.0002175238,0.000009936103],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000935015,"about_ca_system_score_gemma":0.0001581899,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004456388,"about_ca_topic_score_gemma":0.000003631444,"domain_scores_codex":[0.9985863,3.158086e-8,0.0006994174,0.0001873786,0.0002792657,0.0002476252],"domain_scores_gemma":[0.9987464,0.00004653082,0.0006087822,0.0003586469,0.0001557671,0.00008386745],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003360436,0.0001985741,0.0006962193,0.001306366,0.0001584771,0.000003551329,0.0009920857,0.00001838507,0.5895291,0.000802017,0.0005007485,0.4054584],"study_design_scores_gemma":[0.0006331704,0.00005646577,0.00709578,0.0001934379,0.00004533448,0.00001290759,0.0005944007,0.0000245937,0.9885859,0.0001437483,0.002394039,0.0002201747],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.4837095,0.00004135062,0.000001704976,0.00006595059,0.00002648154,0.00006089404,0.00002951158,0.0000517124,0.5160129],"genre_scores_gemma":[0.9841222,0.00003023928,0.0000757492,0.00002277245,0.00009110147,0.000006103281,0.0001420385,0.0000142468,0.01549562],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.5005173,"threshold_uncertainty_score":0.9978943,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01238663077723387,"score_gpt":0.2339840942852483,"score_spread":0.2215974635080144,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}