{"id":"W2951580475","doi":"10.1002/chin.200522068","title":"Unprecedented Catalytic Asymmetric Reduction of N—H Imines.","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Merck Canada Inc. (Canada)","funders":"","keywords":"Chemistry; Reduction (mathematics); Catalysis; Medicinal chemistry; Combinatorial chemistry; Stereochemistry; Organic chemistry; Geometry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002334161,0.0006261644,0.0003470492,0.0002289839,0.0003433002,0.0003601117,0.001071415,0.0006699789,0.002955331],"category_scores_gemma":[0.0002690058,0.0002239231,0.0002423107,0.0001789978,0.0003791042,0.0006598872,0.0008556601,0.001155881,0.001667037],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004937871,"about_ca_system_score_gemma":0.000280363,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007113043,"about_ca_topic_score_gemma":0.001545432,"domain_scores_codex":[0.9997453,0.00004473081,0.00001038663,0.00005231722,0.0000585772,0.00008868788],"domain_scores_gemma":[0.9999647,0.000007605127,0.000007792824,0.000006949494,0.00000514386,0.000007797819],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005007142,0.0003992931,0.0002835182,0.001889854,0.0001309354,0.001921542,0.0005220939,0.001709238,0.8726838,0.02048947,0.02988041,0.06958909],"study_design_scores_gemma":[0.0001520323,0.0004201055,0.0006195367,0.00004647371,0.00003175724,0.001111268,0.0001047569,0.004533641,0.9157491,0.002717892,0.07446258,0.00005083308],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5700026,0.01397147,0.07775816,0.004068311,0.003133058,0.0006417049,0.002235472,0.002161524,0.3260278],"genre_scores_gemma":[0.9678177,0.002934102,0.009164904,0.0005026445,0.000163435,0.0001190704,0.0004487528,0.00007894306,0.01877042],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002955331,"threshold_uncertainty_score":0.009886503,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01077181487234711,"score_gpt":0.2278141643877974,"score_spread":0.2170423495154503,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}