{"id":"W2951614264","doi":"10.1002/chin.201511072","title":"ChemInform Abstract: Metal‐Free Metathesis Reaction of C‐Chiral Allylic Sulfilimines with Aryl Isocyanates: Construction of Chiral Nonracemic Allylic Isocyanates.","year":2015,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Allylic rearrangement; Thiocarbamates; Aryl; Nucleophile; Organic chemistry; Medicinal chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002035226,0.0004364286,0.0001109642,0.0004105003,0.0002069082,0.0003734932,0.0004748348,0.0003124624,0.009615726],"category_scores_gemma":[0.0001595855,0.0001810518,0.0001334364,0.0002341113,0.0001846836,0.0003357418,0.000314153,0.0005628287,0.002991725],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000515733,"about_ca_system_score_gemma":0.0005887945,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004008762,"about_ca_topic_score_gemma":0.001166714,"domain_scores_codex":[0.9998913,0.00001366576,0.000005766792,0.00002121267,0.00004868867,0.00001943872],"domain_scores_gemma":[0.9999377,0.000008316501,0.00001455771,0.00001115728,0.00001306858,0.0000152005],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002631088,0.0001320675,0.0004654523,0.0001889904,0.00001685265,0.000187712,0.00009212406,0.0004528627,0.949693,0.008179311,0.002851728,0.03747677],"study_design_scores_gemma":[0.00002650093,0.000115404,0.0005076658,0.000009626429,0.00001177584,0.0001668933,0.00001309298,0.0008194034,0.9786351,0.0002301314,0.01945789,0.000006504778],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6896744,0.00374986,0.07732507,0.001241907,0.000308631,0.0003891366,0.003355487,0.004181844,0.2197736],"genre_scores_gemma":[0.9350402,0.001898686,0.02767392,0.0002113064,0.00004489307,0.00009807765,0.002362365,0.0002052202,0.03246531],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009615726,"threshold_uncertainty_score":0.03216779,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02572625668971115,"score_gpt":0.2533547216228854,"score_spread":0.2276284649331742,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}