{"id":"W2951630512","doi":"10.1002/chin.200052188","title":"ChemInform Abstract: The Use of the Ramberg—Baecklund Rearrangement for the Formation of Aza‐Macrocycles: A Total Synthesis of Manzamine C.","year":2000,"lang":"en","type":"article","venue":"ChemInform","topic":"Marine Sponges and Natural Products","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"","keywords":"Chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003811682,0.0008486758,0.000650411,0.0007371879,0.0005432022,0.000514114,0.001159255,0.0005576834,0.006448823],"category_scores_gemma":[0.0003395682,0.0003192136,0.000507865,0.0006121341,0.0004834991,0.0008148735,0.0007957724,0.001057198,0.003614801],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006756554,"about_ca_system_score_gemma":0.001166062,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001624962,"about_ca_topic_score_gemma":0.001284505,"domain_scores_codex":[0.9997584,0.00003884338,0.00001809123,0.00005212472,0.00006533667,0.00006720725],"domain_scores_gemma":[0.9999405,0.000009544587,0.00001041986,0.0000113069,0.000007099201,0.00002106694],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0008167623,0.0001913212,0.0001796607,0.001364679,0.0001451389,0.001206014,0.0004686754,0.00224129,0.8601199,0.02202598,0.01191109,0.09932949],"study_design_scores_gemma":[0.0002542479,0.001691002,0.001149027,0.0001044192,0.00009517008,0.001452776,0.00008242908,0.00246295,0.8981835,0.002939997,0.09142342,0.0001609556],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.5159585,0.0440449,0.206506,0.003311003,0.003348318,0.002339462,0.006716508,0.005300191,0.2124751],"genre_scores_gemma":[0.9146231,0.02053658,0.03057009,0.0005045768,0.0001592624,0.0004286406,0.001719865,0.0003868654,0.03107095],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.006448823,"threshold_uncertainty_score":0.02157348,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01730414048072778,"score_gpt":0.2326852096586832,"score_spread":0.2153810691779554,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}