{"id":"W2951672921","doi":"10.1021/ol1026409","title":"Palladium-Catalyzed Cross-Coupling of Cyclopropanols with Aryl Halides Under Mild Conditions","year":2010,"lang":"en","type":"article","venue":"Organic Letters","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":76,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Halide; Palladium; Aryl; Catalysis; Intermolecular force; Coupling (piping); Combinatorial chemistry; Polymer chemistry; Organic chemistry; Molecule; Alkyl; Metallurgy","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002670165,0.0007400953,0.0002241196,0.0003092964,0.0003012062,0.0002511011,0.0004574788,0.0003131301,0.003393681],"category_scores_gemma":[0.0002345239,0.0002923177,0.0002517569,0.0003339053,0.0002681086,0.0003673916,0.0003995163,0.0007613737,0.001151186],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002678863,"about_ca_system_score_gemma":0.0002890101,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007327743,"about_ca_topic_score_gemma":0.001618551,"domain_scores_codex":[0.9998123,0.00002198137,0.00001353761,0.00004456774,0.00004189771,0.0000656053],"domain_scores_gemma":[0.9999081,0.00002171742,0.00002039815,0.00001881385,0.00001419297,0.000016821],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001561997,0.00003876529,0.0001241466,0.0001926252,0.00002704992,0.0002702474,0.00006653584,0.0002291397,0.9930884,0.0006785733,0.0003144998,0.004813977],"study_design_scores_gemma":[0.000008952658,0.00005414402,0.0001889509,0.00000286303,0.00000989845,0.0001034273,0.000008441809,0.0001267005,0.99771,0.00004647602,0.00173658,0.000003583156],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.929328,0.005818939,0.03595528,0.0003537207,0.0001801503,0.0001926587,0.0005558974,0.0005541885,0.02706121],"genre_scores_gemma":[0.9854025,0.002863336,0.004530448,0.00008659053,0.00002916908,0.00007848045,0.0004589609,0.00005494966,0.0064957],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003393681,"threshold_uncertainty_score":0.01135302,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01002939845499312,"score_gpt":0.242522024112395,"score_spread":0.2324926256574019,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}