{"id":"W2951731424","doi":"10.1139/v03-174","title":"Generic synthesis of β-sultams via domino alkylation of bromomethanesulfonamides","year":2004,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Intramolecular force; Alkylation; Nitrile; Bicyclic molecule; Ketone; Ring (chemistry); Intermolecular force; Medicinal chemistry; Isomerization; Stereochemistry; Organic chemistry; Catalysis; Molecule","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001573656,0.0004107526,0.0002291424,0.0002235545,0.0001171571,0.0001740809,0.0003542207,0.0001907599,0.002024729],"category_scores_gemma":[0.0001482254,0.0001578826,0.0001962028,0.000185671,0.0001680549,0.0001773667,0.0002511957,0.0003117149,0.0007072999],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002715709,"about_ca_system_score_gemma":0.0002411939,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002929489,"about_ca_topic_score_gemma":0.0008587358,"domain_scores_codex":[0.9999121,0.00001203341,0.000009986286,0.00001768407,0.00002046858,0.00002756309],"domain_scores_gemma":[0.9999491,0.000006835124,0.0000171817,0.000007634562,0.000008745717,0.00001057765],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001021936,0.00003009058,0.0001168464,0.000136274,0.00001420644,0.0002547752,0.00006599992,0.0003511451,0.9880946,0.001394932,0.0001807778,0.009258025],"study_design_scores_gemma":[0.00003388729,0.0003925815,0.0005345222,0.000008611227,0.00001779183,0.0003719759,0.00001675303,0.0005161152,0.9865749,0.0001450384,0.01137901,0.000008907993],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.9346359,0.003542079,0.03214882,0.0001975782,0.0001191373,0.0004067901,0.0008793029,0.000547452,0.02752298],"genre_scores_gemma":[0.9759976,0.002716403,0.01406815,0.0000786816,0.0000200034,0.0001176104,0.0003851571,0.00004501775,0.006571317],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.002024729,"threshold_uncertainty_score":0.006773412,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01234505834576945,"score_gpt":0.2230013557168048,"score_spread":0.2106562973710353,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}