{"id":"W2951731769","doi":"10.1021/ic001167w","title":"X-ray Crystal Structures of α-KrF<sub>2</sub>, [KrF][MF<sub>6</sub>] (M = As, Sb, Bi), [Kr<sub>2</sub>F<sub>3</sub>][SbF<sub>6</sub>]·KrF<sub>2</sub>, [Kr<sub>2</sub>F<sub>3</sub>]<sub>2</sub>[SbF<sub>6</sub>]<sub>2</sub>·KrF<sub>2</sub>, and [Kr<sub>2</sub>F<sub>3</sub>][AsF<sub>6</sub>]·[KrF][AsF<sub>6</sub>]; Synthesis and Characterization of [Kr<sub>2</sub>F<sub>3</sub>][PF<sub>6</sub>]·<i>n</i>KrF<sub>2</sub>; and Theoretical Studies of KrF<sub>2</sub>, KrF<sup>+</sup>, Kr<sub>2</sub>F<sub>3</sub><sup>+</sup>, and the [KrF][MF<sub>6</sub>] (M = P, As, Sb, Bi) Ion Pairs","year":2001,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":77,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Monoclinic crystal system; Isostructural; Crystallography; Tetragonal crystal system; Chemistry; Crystal structure; Group (periodic table); X-ray crystallography; Crystal (programming language); Diffraction; Physics; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity"],"category_scores_codex":[0.03363859,0.05937343,0.05375696,0.02453891,0.02557549,0.01767313,0.03589262,0.04443273,0.0005835298],"category_scores_gemma":[0.02290599,0.06559972,0.02841679,0.04594195,0.04416661,0.02521422,0.03111763,0.05340397,0.008273106],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.02726534,"about_ca_system_score_gemma":0.02423273,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008913972,"about_ca_topic_score_gemma":0.00489406,"domain_scores_codex":[0.7992747,0.01963526,0.05019869,0.04834749,0.03620528,0.0463385],"domain_scores_gemma":[0.8464342,0.02327466,0.04167643,0.03800213,0.0220511,0.02856153],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.02584411,0.01821485,0.004103092,0.01982436,0.02754521,0.01106298,0.01093074,0.004801227,0.7667213,0.001609299,0.02651448,0.08282833],"study_design_scores_gemma":[0.05229056,0.008189141,0.004547897,0.01885242,0.02735779,0.01757717,0.01257865,0.007843087,0.7888325,0.007173916,0.003184058,0.05157284],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8653843,0.03104753,0.002784038,0.005279171,0.01782054,0.03422828,0.02555886,0.01605946,0.00183778],"genre_scores_gemma":[0.7766944,0.1425103,0.0007421285,0.006366522,0.01953385,0.01300286,0.02230299,0.01871756,0.0001294065],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1114628,"threshold_uncertainty_score":0.9950724,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006312861213549678,"score_gpt":0.2025240285227121,"score_spread":0.1962111673091625,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}