{"id":"W2951731769","doi":"10.1021/ic001167w","title":"X-ray Crystal Structures of α-KrF<sub>2</sub>, [KrF][MF<sub>6</sub>] (M = As, Sb, Bi), [Kr<sub>2</sub>F<sub>3</sub>][SbF<sub>6</sub>]·KrF<sub>2</sub>, [Kr<sub>2</sub>F<sub>3</sub>]<sub>2</sub>[SbF<sub>6</sub>]<sub>2</sub>·KrF<sub>2</sub>, and [Kr<sub>2</sub>F<sub>3</sub>][AsF<sub>6</sub>]·[KrF][AsF<sub>6</sub>]; Synthesis and Characterization of [Kr<sub>2</sub>F<sub>3</sub>][PF<sub>6</sub>]·<i>n</i>KrF<sub>2</sub>; and Theoretical Studies of KrF<sub>2</sub>, KrF<sup>+</sup>, Kr<sub>2</sub>F<sub>3</sub><sup>+</sup>, and the [KrF][MF<sub>6</sub>] (M = P, As, Sb, Bi) Ion Pairs","year":2001,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":77,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Monoclinic crystal system; Isostructural; Crystallography; Tetragonal crystal system; Chemistry; Crystal structure; Group (periodic table); X-ray crystallography; Crystal (programming language); Diffraction; Physics; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001014105,0.0002613475,0.0002176666,0.0001925048,0.0003950848,0.0001786501,0.0004757568,0.0004140334,0.004580286],"category_scores_gemma":[0.0003876592,0.0001675084,0.00009546515,0.0003904382,0.0001647574,0.0002232935,0.0001132225,0.0004201673,0.0004389075],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004124266,"about_ca_system_score_gemma":0.0004818148,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.008050092,"about_ca_topic_score_gemma":0.01221889,"domain_scores_codex":[0.9999334,0.000005279707,0.000003537381,0.00001238331,0.0000331241,0.00001221652],"domain_scores_gemma":[0.9999243,0.000008724833,0.00002073732,0.000005904587,0.00003030571,0.000009989856],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006281393,0.0000582533,0.00216029,0.001012926,0.00003034025,0.0002642249,0.0003640804,0.003642549,0.95087,0.006631599,0.01404823,0.02028948],"study_design_scores_gemma":[0.0001841258,0.0005012783,0.02574601,0.0001095686,0.00005997786,0.0009307151,0.0008655476,0.008639402,0.7925585,0.001291846,0.169013,0.0001000362],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9664324,0.002339308,0.004438236,0.0003898603,0.0001325765,0.0001128958,0.004888983,0.0001805337,0.02108521],"genre_scores_gemma":[0.9703149,0.001689175,0.007889731,0.0001807735,0.0000213677,0.000135336,0.007828901,0.0000626527,0.01187721],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008050092,"threshold_uncertainty_score":0.01600647,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006312861213549678,"score_gpt":0.2025240285227121,"score_spread":0.1962111673091625,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}