{"id":"W2951732769","doi":"10.1002/chin.201003084","title":"ChemInform Abstract: A Novel P,O‐Type Phosphorinane Ligand for the Suzuki—Miyaura Cross‐Coupling of Aryl Chlorides.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Aryl; Ligand (biochemistry); Combinatorial chemistry; Coupling (piping); Type (biology); Service (business); Stereochemistry; Medicinal chemistry; Organic chemistry; Biochemistry; Business; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003285161,0.000403801,0.0004450563,0.00005583645,0.000329328,0.0001906324,0.0006843706,0.0003219795,0.0004888264],"category_scores_gemma":[0.0005868786,0.0003363726,0.0003447673,0.0003369169,0.0002819581,0.0003954213,0.00009661863,0.0004369677,0.00003419078],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002690767,"about_ca_system_score_gemma":0.0002670457,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009678096,"about_ca_topic_score_gemma":0.000007221849,"domain_scores_codex":[0.9976816,6.811365e-11,0.0008761621,0.0003722695,0.0004257223,0.0006443118],"domain_scores_gemma":[0.9973831,0.0004803256,0.0005246353,0.000988497,0.0004636479,0.0001598145],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000303523,0.0001617714,0.00009038597,0.0003057748,0.0000942996,0.000001934259,0.0006016392,0.00005165236,0.964045,0.0002335762,0.002848728,0.03126166],"study_design_scores_gemma":[0.00133892,0.00003714665,0.001375332,0.0001302539,0.00009906526,0.00005376601,0.0003695292,0.0005570439,0.9847117,0.00009339186,0.01084629,0.0003875315],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9764801,0.0004479486,0.00000121814,0.0001696529,0.0003487283,0.000309937,0.0001287233,0.0001708592,0.0219428],"genre_scores_gemma":[0.9815278,0.0001165743,0.00000763664,0.00006610643,0.0004792415,0.000054903,0.0001995178,0.0000459711,0.01750226],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03087412,"threshold_uncertainty_score":0.9999088,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02391732931412914,"score_gpt":0.29087073477424,"score_spread":0.2669534054601108,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}