{"id":"W2951750876","doi":"10.1021/jo026237q","title":"The Pd<sub>3</sub>(dppm)<sub>3</sub>(CO)<sup>2+</sup>Cluster: An Efficient Electrochemically Assisted Lewis Acid Catalyst for the Fluorination and Alcoholysis of Acyl Chlorides","year":2002,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Catalysis; Lewis acids and bases; Cluster (spacecraft); Chemistry; Organic chemistry; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001032833,0.0004198899,0.0005509596,0.00003855212,0.0007320065,0.0001396965,0.001055026,0.0003123049,0.0001332166],"category_scores_gemma":[0.001023028,0.0002351396,0.0004345862,0.0003648468,0.0004312826,0.0001389994,0.0001526562,0.0008488997,0.000006129105],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003174206,"about_ca_system_score_gemma":0.00009875022,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005141092,"about_ca_topic_score_gemma":0.00000527498,"domain_scores_codex":[0.9972669,0.00004324814,0.001073689,0.0003426536,0.0007348369,0.0005386747],"domain_scores_gemma":[0.9957387,0.001621699,0.001082374,0.0008518862,0.0004667994,0.0002385114],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002195867,0.0003065408,0.00003067554,0.0001374842,0.0004871896,0.000001987567,0.0004197642,0.00008791761,0.988158,0.000002331432,0.0009201878,0.009228366],"study_design_scores_gemma":[0.0009894818,0.00004128088,0.00007452686,0.000105685,0.0008175445,0.0006238759,0.0009510323,0.00298324,0.9923536,0.00004740046,0.0007332893,0.0002790993],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949157,0.002268684,0.0002323295,0.001958113,0.0000534617,0.0001601113,0.0000393902,0.00003650396,0.0003357256],"genre_scores_gemma":[0.996881,0.002123049,0.00003756718,0.00004604009,0.0006958204,0.00002041877,0.00002225599,0.00006893879,0.0001049259],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008949268,"threshold_uncertainty_score":0.9588715,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01131978203430115,"score_gpt":0.2184275037827201,"score_spread":0.207107721748419,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}