{"id":"W2951818525","doi":"10.1021/ja992922b","title":"Asymmetric Conjugate Addition of Alkynylboronates to Enones","year":2000,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":101,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Citation; Conjugate; Computer science; Library science; Altmetrics; Information retrieval; World Wide Web; Chemistry; Mathematics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001909974,0.0001171389,0.0003524273,0.00004211478,0.00004973004,0.00001296019,0.0004627877,0.00004998986,0.001426771],"category_scores_gemma":[0.0001898462,0.00008015874,0.0006595295,0.001317656,0.0001980584,0.0000659262,0.00005287758,0.0002429873,0.0000177217],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001337099,"about_ca_system_score_gemma":0.00005084384,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003389987,"about_ca_topic_score_gemma":2.220207e-7,"domain_scores_codex":[0.998716,0.00001973224,0.0004705456,0.0001171443,0.000505319,0.0001712825],"domain_scores_gemma":[0.9986881,0.0001736484,0.0006235332,0.000211099,0.0001711662,0.0001324255],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008460021,0.0002008009,0.0008139246,0.0000236118,0.0003604575,0.000001410365,0.000311952,0.0001160577,0.784205,0.00001118821,0.02604866,0.1878223],"study_design_scores_gemma":[0.0003543075,0.00003526303,0.0005579796,0.0000294573,0.0001139156,0.00003017241,0.0003562478,0.0001498693,0.9636258,0.00008579626,0.03453851,0.0001226624],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9941481,0.0001795066,0.00005848725,0.001189281,0.00002620211,0.00002417062,0.00003492785,0.00001086347,0.004328442],"genre_scores_gemma":[0.9968981,0.0002302795,0.001277084,0.0008865049,0.0001715893,0.000001939326,0.000005177546,0.00001338818,0.0005159419],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1876997,"threshold_uncertainty_score":0.9994861,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006063808248610601,"score_gpt":0.2338988441978458,"score_spread":0.2278350359492352,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}