{"id":"W2951833083","doi":"10.1002/chin.200343148","title":"Alkylation of Phosphine Boranes by Phase‐Transfer Catalysis.","year":2003,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Boranes; Phosphine; Alkylation; Catalysis; Phase (matter); Organic chemistry; Combinatorial chemistry; Boron","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001482768,0.0003952806,0.0002034338,0.000135302,0.0002005239,0.0002152926,0.0003207823,0.000287997,0.004278767],"category_scores_gemma":[0.0002535624,0.0001935369,0.0001564725,0.0001475301,0.0001735759,0.0005382533,0.0003757019,0.0006541873,0.001339763],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002314188,"about_ca_system_score_gemma":0.0003246274,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005211634,"about_ca_topic_score_gemma":0.001064373,"domain_scores_codex":[0.9998963,0.00002035764,0.000006202539,0.0000173803,0.00002022628,0.000039488],"domain_scores_gemma":[0.9999616,0.00001247947,0.000008866947,0.000005853254,0.000006014657,0.000005216484],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006181569,0.00007140129,0.00009923503,0.0006083157,0.00004023788,0.0003145653,0.0001521001,0.0007524529,0.9705079,0.003854303,0.002592211,0.02038921],"study_design_scores_gemma":[0.00009068703,0.0002667919,0.0002126773,0.00002146529,0.00001921171,0.0002510249,0.00002525816,0.0009717359,0.9825771,0.0008013091,0.01475086,0.00001175804],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8554247,0.01424753,0.04885147,0.001545532,0.0006803786,0.0002527315,0.001352073,0.0008584561,0.07678716],"genre_scores_gemma":[0.978695,0.004936727,0.005064995,0.0001530867,0.00004395516,0.00004058657,0.0006728543,0.00007846698,0.01031444],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004278767,"threshold_uncertainty_score":0.01431394,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007027600054701242,"score_gpt":0.2327988739523207,"score_spread":0.2257712738976195,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}