{"id":"W2951835811","doi":"10.1002/hc.20033","title":"Heterocyclizations of hydroxyketones with two‐coordinated (trimethylsilylamino)phosphines, (Me<sub>3</sub>Si)<sub>2</sub>NPESiMe<sub>3</sub>","year":2004,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Heteroatom; Phosphine; Medicinal chemistry; Yield (engineering); Alkyl; Phosphorus; Organic chemistry; Stereochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001374481,0.0003816416,0.0001713206,0.0002058125,0.0001731164,0.000227631,0.0001961177,0.0001774332,0.001914609],"category_scores_gemma":[0.0001683949,0.000147105,0.0001824054,0.0002090331,0.0001857188,0.0002472638,0.0002012955,0.0003182713,0.00048813],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002290861,"about_ca_system_score_gemma":0.0002156165,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004467416,"about_ca_topic_score_gemma":0.001119294,"domain_scores_codex":[0.9998586,0.00001965964,0.00001081876,0.00003616657,0.00003072498,0.00004397639],"domain_scores_gemma":[0.9998589,0.00002559053,0.00004151679,0.0000187477,0.00001463189,0.00004063364],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002193931,0.0000308662,0.0001677968,0.00006295172,0.0000093504,0.0002304148,0.00006465901,0.0003114879,0.9945107,0.000328015,0.0000703822,0.003994036],"study_design_scores_gemma":[0.00001193888,0.0002403017,0.0006836486,0.000003074408,0.00000686762,0.0001037512,0.00001927385,0.0002282678,0.9973465,0.00003706459,0.001315637,0.000003693461],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910042,0.0006286317,0.002674269,0.00003278385,0.00004220552,0.00004194799,0.0001848856,0.00006100318,0.005330066],"genre_scores_gemma":[0.9947018,0.0004274082,0.001981174,0.00002136689,0.000007744176,0.00001977022,0.0002020369,0.00002567361,0.002612976],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001914609,"threshold_uncertainty_score":0.006405056,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007843721868363436,"score_gpt":0.2039173792248562,"score_spread":0.1960736573564927,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}