{"id":"W2951866736","doi":"10.1002/chin.201129047","title":"ChemInform Abstract: A Stereoselective Approach to γ‐Functionalized Carbonyls Exploiting the Cu‐Promoted S<sub>N</sub>2′ Reaction.","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Merck Canada Inc. (Canada)","funders":"","keywords":"Chemistry; Stereoselectivity; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004222642,0.0004409585,0.0004387269,0.0001658447,0.0003039436,0.00008408943,0.0005863041,0.0002861146,0.0006958343],"category_scores_gemma":[0.0004805451,0.0003396804,0.0003331295,0.000890892,0.00009890849,0.0004070255,0.0001749635,0.0004556455,0.0002110265],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004156344,"about_ca_system_score_gemma":0.0001307059,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001796217,"about_ca_topic_score_gemma":0.000005786666,"domain_scores_codex":[0.9975432,2.479767e-7,0.0006875747,0.0005154624,0.0006224566,0.0006310843],"domain_scores_gemma":[0.9980329,0.0001967631,0.0004160426,0.0008248086,0.000261369,0.0002681026],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001394217,0.000213011,0.00004488444,0.0001034834,0.0003268261,0.000002562245,0.004700797,1.207838e-7,0.0706726,0.0001224151,0.004964357,0.9187095],"study_design_scores_gemma":[0.0004577313,0.00001534154,0.001047595,0.00004718401,0.0001437399,0.00004602593,0.005964181,0.00002721326,0.9786044,0.00009061077,0.01308467,0.0004712788],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.07767868,0.00008741495,0.000007654435,0.00003588772,0.00007286004,0.0002208177,0.00002265187,0.0002109213,0.9216631],"genre_scores_gemma":[0.9876003,0.00003066607,0.0001179893,0.0001952173,0.0003755172,0.0005035105,0.0001542707,0.0000654923,0.01095705],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.9182382,"threshold_uncertainty_score":0.9999055,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03084725474703251,"score_gpt":0.2152633061300286,"score_spread":0.184416051382996,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}