{"id":"W2951874427","doi":"10.1002/chin.201409036","title":"ChemInform Abstract: Iridium‐Catalyzed Direct Dehydroxylation of Alcohols.","year":2014,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Iridium; Allylic rearrangement; Catalysis; Allylic alcohol; Alcohol oxidation; Alcohol; Primary (astronomy); Organic chemistry; Simple (philosophy); Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001608446,0.000664027,0.0001843903,0.0003714941,0.0002588192,0.0003097198,0.0006582174,0.0003281707,0.01413376],"category_scores_gemma":[0.0001746467,0.0002031304,0.000120164,0.0002719329,0.0002152078,0.0005734119,0.0005318685,0.000722967,0.00386015],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004399004,"about_ca_system_score_gemma":0.0004542815,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004903612,"about_ca_topic_score_gemma":0.001004696,"domain_scores_codex":[0.9998865,0.00000938662,0.000005968689,0.00003040746,0.00003298804,0.00003467739],"domain_scores_gemma":[0.9999658,0.000004427587,0.000008606684,0.000006120265,0.000006171579,0.000008883091],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009462415,0.0002558262,0.0006158574,0.001721691,0.00006835163,0.0008346587,0.0001637477,0.0009075187,0.8366253,0.01341883,0.03384514,0.1105968],"study_design_scores_gemma":[0.0001257738,0.0002633813,0.0007280697,0.00004464074,0.00003777387,0.0006469658,0.00002913934,0.000590865,0.9141153,0.0005070795,0.08289211,0.00001889918],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.4239364,0.01494185,0.05613797,0.002639242,0.001925219,0.0006375269,0.006875848,0.004588791,0.4883171],"genre_scores_gemma":[0.9428908,0.006818985,0.008344176,0.0003332918,0.0002043498,0.000100915,0.002732672,0.0002248849,0.03835],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.01413376,"threshold_uncertainty_score":0.0472821,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01074743596910544,"score_gpt":0.2320226264283254,"score_spread":0.2212751904592199,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}