{"id":"W2951883220","doi":"10.1002/chin.200831097","title":"ChemInform Abstract: Diastereoselective Bismuth Triflate Catalyzed Claisen Rearrangement of 2‐Alkoxycarbonyl‐Substituted Allyl Vinyl Ethers.","year":2008,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemistry; Claisen rearrangement; Trifluoromethanesulfonate; Bismuth; Catalysis; Organic chemistry; Medicinal chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002990584,0.001025409,0.000342594,0.0006892345,0.0003151018,0.0002776217,0.0007610012,0.0005673151,0.008652362],"category_scores_gemma":[0.000251313,0.0002206377,0.0003656303,0.0003929443,0.0002260659,0.0006665493,0.0003993537,0.0007651333,0.003053569],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006076797,"about_ca_system_score_gemma":0.0007977613,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00136926,"about_ca_topic_score_gemma":0.003239478,"domain_scores_codex":[0.9997867,0.0000231257,0.00001013663,0.00003107744,0.00004107159,0.0001079034],"domain_scores_gemma":[0.9999514,0.000007692506,0.00001298689,0.000005895496,0.000006017418,0.00001612121],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009594189,0.0004827368,0.0003667528,0.001607262,0.0001937537,0.001753369,0.0004676058,0.002772134,0.8847848,0.01206762,0.0280284,0.06651621],"study_design_scores_gemma":[0.0001994676,0.0009236159,0.001355695,0.0001019712,0.00006145032,0.001065581,0.00009782962,0.002920788,0.9529894,0.001072182,0.03914088,0.00007105082],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7622351,0.008054235,0.03890164,0.001566675,0.001772874,0.0007244595,0.005689779,0.002801675,0.1782535],"genre_scores_gemma":[0.9674717,0.004501379,0.006326845,0.0003265652,0.00008900822,0.00009078591,0.001713356,0.0001760399,0.01930432],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008652362,"threshold_uncertainty_score":0.02894503,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02820976950279479,"score_gpt":0.2614113870093647,"score_spread":0.2332016175065699,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}