{"id":"W2951890707","doi":"10.1021/om060049z","title":"A Family of Active Iridium Catalysts for Transfer Hydrogenation of Ketones","year":2006,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":200,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University; University of Toronto","funders":"","keywords":"Chemistry; Iridium; Catalysis; Transfer hydrogenation; Pincer ligand; Pincer movement; Ligand (biochemistry); Propanol; Base (topology); Medicinal chemistry; Polymer chemistry; Combinatorial chemistry; Organic chemistry; Methanol; Ruthenium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002004791,0.0004219655,0.0002964129,0.0003601275,0.0001911437,0.0004526939,0.0006893881,0.000268985,0.0009567687],"category_scores_gemma":[0.0002259664,0.0001955755,0.0001582134,0.0001851678,0.0002655628,0.000448716,0.0004163595,0.0005321197,0.0003478362],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003873734,"about_ca_system_score_gemma":0.0001271587,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002657039,"about_ca_topic_score_gemma":0.0003823892,"domain_scores_codex":[0.9998246,0.00001764408,0.00001223891,0.0000335135,0.00006836018,0.00004354712],"domain_scores_gemma":[0.9999,0.00001334917,0.00001938919,0.00001737171,0.00001739074,0.00003241815],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002995201,0.00009666887,0.0005366303,0.0002579573,0.00002876483,0.0003359319,0.0001514097,0.0004386633,0.9744269,0.00270262,0.0006668753,0.02005818],"study_design_scores_gemma":[0.00008533204,0.0003660345,0.001159286,0.00001026289,0.00002723664,0.0007363325,0.00003086124,0.001123357,0.9778444,0.0003178575,0.0182779,0.0000211471],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9679033,0.006662037,0.01221828,0.0003005273,0.0001040088,0.0001004818,0.0003943913,0.0004466227,0.0118704],"genre_scores_gemma":[0.9884375,0.002015779,0.004633411,0.00004788398,0.00002252917,0.00004169212,0.0005111137,0.00003135003,0.004258741],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009567687,"threshold_uncertainty_score":0.00320071,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01031857374619974,"score_gpt":0.2192846952844268,"score_spread":0.2089661215382271,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}