{"id":"W2951894480","doi":"10.1002/chin.200852060","title":"ChemInform Abstract: Sterically Biased 3,3‐Sigmatropic Rearrangement of Chiral Allylic Azides: Application to the Total Syntheses of Alkaloids.","year":2008,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Allylic rearrangement; Steric effects; Sigmatropic reaction; Stereochemistry; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003234399,0.0005946426,0.0003665625,0.0003522151,0.0003313351,0.0004180343,0.0004731992,0.0003416983,0.01012184],"category_scores_gemma":[0.0001850558,0.0002521781,0.0002929427,0.0003292101,0.0003073264,0.0005149883,0.0005447766,0.000843256,0.003288822],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003516335,"about_ca_system_score_gemma":0.000610592,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004070891,"about_ca_topic_score_gemma":0.0008530164,"domain_scores_codex":[0.9998473,0.00001929609,0.000009049415,0.00003315706,0.00005202129,0.00003916615],"domain_scores_gemma":[0.9999408,0.00001042372,0.00001406137,0.000008374898,0.000008406611,0.00001792077],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007763589,0.0001387164,0.0001557321,0.0007673507,0.00006484535,0.0004033157,0.0001494807,0.001527355,0.9281302,0.006194946,0.01031558,0.05137606],"study_design_scores_gemma":[0.0001959804,0.0009964801,0.0005328376,0.00004376569,0.00004058948,0.0004428553,0.00004028794,0.003211165,0.9664907,0.0009535736,0.02700632,0.00004551415],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6389171,0.0184585,0.1559457,0.002088012,0.002361418,0.0007706998,0.004360552,0.005206758,0.1718913],"genre_scores_gemma":[0.929353,0.009034171,0.01824755,0.0004835786,0.0002257015,0.0001712283,0.001588661,0.0003513839,0.04054478],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01012184,"threshold_uncertainty_score":0.03386098,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02491326396886134,"score_gpt":0.2622366399972009,"score_spread":0.2373233760283395,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}