{"id":"W2951906413","doi":"10.1002/chin.200548064","title":"Ti‐Catalyzed Reactions of Hindered Isocyanates with Alcohols.","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Catalysis; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002622066,0.0005874103,0.0002465072,0.000311885,0.0002433651,0.0003195449,0.0006913234,0.0002595529,0.006155308],"category_scores_gemma":[0.0004017521,0.000154079,0.0002846094,0.0002556642,0.0002971706,0.0005226842,0.0005146695,0.001011521,0.001706873],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005571297,"about_ca_system_score_gemma":0.0004783873,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001610734,"about_ca_topic_score_gemma":0.00258709,"domain_scores_codex":[0.9997851,0.0000451249,0.00001086795,0.0000229357,0.00003933237,0.00009662619],"domain_scores_gemma":[0.9999388,0.0000151388,0.00001034002,0.0000101133,0.00001333267,0.0000122223],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001255106,0.0002652423,0.0003669841,0.001379989,0.0001187679,0.0007244047,0.0004557123,0.00192879,0.9214246,0.02881524,0.006897035,0.03636822],"study_design_scores_gemma":[0.00004608596,0.0003019549,0.0002218978,0.00002960486,0.00002743172,0.0001757634,0.00004531896,0.0008851243,0.9798192,0.000756168,0.017675,0.000016467],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7277825,0.01934778,0.03466307,0.001143513,0.002678611,0.0003339597,0.0006262961,0.0007447401,0.2126795],"genre_scores_gemma":[0.9620124,0.007441529,0.002801938,0.0001426212,0.00009705379,0.00005694821,0.0004601661,0.00006517126,0.02692218],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006155308,"threshold_uncertainty_score":0.02059156,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0117327651220321,"score_gpt":0.2251631778407081,"score_spread":0.213430412718676,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}