{"id":"W2951908692","doi":"10.1080/10426500108546604","title":"Synthesis of New Phosphino-Amines, their Metal Complexes and their Application in Catalysis","year":2001,"lang":"en","type":"article","venue":"Phosphorus, sulfur, and silicon and the related elements","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Engineering and Physical Sciences Research Council; University of Windsor","keywords":"Hydroformylation; Chemistry; Rhodium; Palladium; Catalysis; Transition metal; Alkylation; Metal; Medicinal chemistry; Tsuji–Trost reaction; Allylic rearrangement; Condensation; Polymer chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004658339,0.000348801,0.0007502999,0.000110887,0.0001764522,0.00005648703,0.0002481557,0.0001340481,0.000829171],"category_scores_gemma":[0.00007103306,0.0002264928,0.0001455389,0.0003544451,0.0003225109,0.0001205992,0.0001793542,0.0001774115,0.00000483178],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002770663,"about_ca_system_score_gemma":0.0000195562,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002949705,"about_ca_topic_score_gemma":0.0002700221,"domain_scores_codex":[0.9982554,0.00005510191,0.0007048498,0.0004959771,0.0001721522,0.0003165569],"domain_scores_gemma":[0.9986743,0.0003846872,0.0002865963,0.000479834,0.00003448953,0.000140105],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000461124,0.0003538475,0.04931987,0.0001265073,0.001390375,0.000003370768,0.003642167,0.000003958974,0.08530955,0.003569686,0.00004018904,0.8557793],"study_design_scores_gemma":[0.01050105,0.00009270256,0.06041448,0.0002863029,0.001607673,0.0001387852,0.01062844,0.008097912,0.839192,0.01565268,0.05181501,0.001572984],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9705018,0.0262385,0.00001765323,0.000409917,0.00001749797,0.0001994252,0.00004669305,0.00003419998,0.002534326],"genre_scores_gemma":[0.978799,0.0200546,0.00001740778,0.00004203953,0.00002135485,0.00004837136,0.00005996503,0.00002804596,0.0009291497],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.8542064,"threshold_uncertainty_score":0.923611,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00879520168542066,"score_gpt":0.2086843477757019,"score_spread":0.1998891460902812,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}