{"id":"W2951913084","doi":"10.1021/ol006695q","title":"B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>-Catalyzed Hydrosilation of Imines via Silyliminium Intermediates","year":2000,"lang":"en","type":"article","venue":"Organic Letters","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":346,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Catalysis; Counterion; Hydride; Medicinal chemistry; Ion; Organic chemistry; Metal","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0002693383,0.001129547,0.001103817,0.000215005,0.0002749899,0.0001607478,0.001063463,0.0008220931,0.001179473],"category_scores_gemma":[0.0002079656,0.001232457,0.0004900226,0.0007429078,0.0005601114,0.0005691,0.0002825487,0.0009475167,0.001202157],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005235953,"about_ca_system_score_gemma":0.0002200929,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001934466,"about_ca_topic_score_gemma":0.00004702351,"domain_scores_codex":[0.9947671,0.00008313888,0.001492894,0.001447155,0.0009251077,0.001284649],"domain_scores_gemma":[0.9967399,0.0003114117,0.0007012687,0.001558322,0.0001631447,0.0005259045],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001738447,0.0003290469,0.0025954,0.0005374379,0.0002273299,0.00007246605,0.0007882678,0.00001332379,0.98185,0.000001811185,0.004643651,0.008767368],"study_design_scores_gemma":[0.002233729,0.00004471766,0.002413581,0.0002274887,0.0003047329,0.0001210242,0.0001720949,0.0001631246,0.9928701,0.0000277542,0.0001652135,0.001256477],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9952482,0.0002573335,0.0000535494,0.002672408,0.000516027,0.0002857453,0.0001492539,0.0005608016,0.0002567079],"genre_scores_gemma":[0.9952376,0.0004950799,0.00003839383,0.001923255,0.001217588,0.00004717708,0.0006667263,0.0003494883,0.00002464124],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01102001,"threshold_uncertainty_score":0.9997336,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005073518061244146,"score_gpt":0.1900126229998803,"score_spread":0.1849391049386362,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}