{"id":"W2951927455","doi":"10.1139/v05-031","title":"Synthesis of acetylenic ketones by a Pd-catalyzed carbonylative three-component coupling reaction in [bmim]PF<sub>6</sub>","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":57,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Sonogashira coupling; Ionic liquid; Catalysis; Carbonylation; Coupling reaction; Palladium; Aryl; Component (thermodynamics); Organic chemistry; Medicinal chemistry; Carbon monoxide; Alkyl","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000363008,0.0002987177,0.0005776776,0.0001724795,0.0001118128,0.00005583817,0.0004016506,0.0003077796,0.0001675791],"category_scores_gemma":[0.0005192173,0.0003412298,0.0002741996,0.0002846018,0.0002478528,0.0002552526,0.00002482312,0.0007650447,0.000008931375],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001488458,"about_ca_system_score_gemma":0.001384467,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003194439,"about_ca_topic_score_gemma":0.008163827,"domain_scores_codex":[0.997879,0.000001674545,0.0009755327,0.0002999413,0.0003530581,0.0004907509],"domain_scores_gemma":[0.9975913,0.0002979462,0.0008194257,0.0004342728,0.0002725448,0.000584551],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006571396,0.000073417,0.002831837,0.0001424574,0.000128064,0.00004481567,0.000315351,0.0006273536,0.9934242,0.000001118642,0.0002610461,0.002084662],"study_design_scores_gemma":[0.0006865372,0.000005294077,0.0006382779,0.000514654,0.0001027639,0.0003092847,0.0005821177,0.001001658,0.9953249,0.0000290823,0.0005162975,0.0002891684],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.997445,0.001145654,0.00001166235,0.0003867905,0.0001050424,0.00005575984,0.0001447368,0.00001672596,0.0006885951],"genre_scores_gemma":[0.9993576,0.00008273811,0.00002307812,0.000009264573,0.0003425029,0.0000108786,0.00003947382,0.00005233627,0.00008213538],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004969387,"threshold_uncertainty_score":0.999904,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00864137417954638,"score_gpt":0.2176507347546371,"score_spread":0.2090093605750907,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}