{"id":"W2951947795","doi":"10.1002/chin.200833096","title":"ChemInform Abstract: Palladium‐Catalyzed Thiocarbonylation of Iodoarenes with Thiols in Phosphonium Salt Ionic Liquids.","year":2008,"lang":"en","type":"article","venue":"ChemInform","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Phosphonium; Salt (chemistry); Palladium; Phosphonium salt; Ionic bonding; Catalysis; Ionic liquid; Combinatorial chemistry; Organic chemistry; Polymer chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002206131,0.0007038345,0.0002431607,0.0003074797,0.0002007224,0.0002736387,0.0006326691,0.0003080304,0.005370181],"category_scores_gemma":[0.0002168445,0.0001962208,0.0003093675,0.0003592202,0.0002109424,0.0005885735,0.0003412644,0.0007176528,0.002750855],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004182477,"about_ca_system_score_gemma":0.0005432581,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005994802,"about_ca_topic_score_gemma":0.001145486,"domain_scores_codex":[0.9998591,0.0000146632,0.00001032875,0.00002988073,0.00004434055,0.00004164071],"domain_scores_gemma":[0.9999424,0.000007976444,0.00001813142,0.0000085594,0.000008735914,0.00001418138],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003475727,0.00008074271,0.00009972324,0.0008740695,0.0000584879,0.0003822245,0.0001098401,0.000596591,0.9724814,0.002599763,0.004072519,0.01829707],"study_design_scores_gemma":[0.00002876089,0.0002466769,0.000180283,0.00001482607,0.00002114362,0.0002018663,0.00001028276,0.0003806407,0.9881681,0.0001242451,0.01061256,0.00001078845],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8007176,0.02060781,0.06192631,0.001373634,0.001610247,0.0003514289,0.003871204,0.004257339,0.1052844],"genre_scores_gemma":[0.9515155,0.00786127,0.00814073,0.0002190744,0.0001165988,0.00004994218,0.001528495,0.0002275282,0.03034093],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005370181,"threshold_uncertainty_score":0.01796502,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01561479004836691,"score_gpt":0.2298290396402398,"score_spread":0.2142142495918729,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}