{"id":"W2952003792","doi":"10.1002/chin.201639159","title":"ChemInform Abstract: Optimization and Multigram Scalability of a Catalytic Enantioselective Borylative Migration for the Synthesis of Functionalized Chiral Piperidines.","year":2016,"lang":"en","type":"article","venue":"ChemInform","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Alberta","funders":"","keywords":"Enantioselective synthesis; Chemistry; Scalability; Citation; Library science; Information retrieval; Combinatorial chemistry; Stereochemistry; Mathematical economics; Catalysis; Computer science; Organic chemistry; Database; Mathematics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007705498,0.00150254,0.0004993898,0.0008688316,0.0004409393,0.0007208713,0.0008967931,0.0006538539,0.013266],"category_scores_gemma":[0.0005123221,0.0005851279,0.0002844268,0.0005205584,0.0003377889,0.0006723198,0.0005828089,0.001166568,0.007121068],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007178273,"about_ca_system_score_gemma":0.001147229,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001239583,"about_ca_topic_score_gemma":0.003261243,"domain_scores_codex":[0.9995264,0.00005817688,0.00002565862,0.0001117701,0.0002104265,0.00006769295],"domain_scores_gemma":[0.9997948,0.00005600183,0.00003148034,0.00002874486,0.00005173152,0.00003733947],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009638502,0.0003428924,0.000256889,0.0004467813,0.00004293967,0.000150971,0.00009198368,0.001334547,0.9238881,0.001904609,0.01080947,0.05976693],"study_design_scores_gemma":[0.00007632613,0.0002470397,0.0002655467,0.00001410645,0.00002347993,0.0001254495,0.00001299366,0.002657722,0.9794957,0.0001070512,0.01695256,0.00002194351],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5587545,0.008245445,0.1976463,0.002189358,0.0006251913,0.001384165,0.01959458,0.02849687,0.1830635],"genre_scores_gemma":[0.7769885,0.005253297,0.1625834,0.0004577257,0.0001164014,0.0006039013,0.01421945,0.002098812,0.03767849],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.013266,"threshold_uncertainty_score":0.04437917,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01017928787888313,"score_gpt":0.2279208712774631,"score_spread":0.21774158339858,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}