{"id":"W2952045012","doi":"10.1055/s-2000-7155","title":"Enolates of Thiabicyclic Ketones as Stepping Stones Towards Synthesis of Sulfur Analogs of Tropane Alkaloids","year":2000,"lang":"en","type":"article","venue":"Synlett","topic":"Advanced Synthetic Organic Chemistry","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada; University of Saskatchewan","keywords":"Chemistry; Tropane; Enantioselective synthesis; Bicyclic molecule; Lithium (medication); Ketone; Sulfur; Deprotonation; Selectivity; Organic chemistry; Stereochemistry; Medicinal chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001893042,0.0003176423,0.0008506242,0.00007451871,0.00004508419,0.00000620548,0.0005328081,0.0002453573,0.00878616],"category_scores_gemma":[0.0005431731,0.0003120536,0.0002441918,0.0002741036,0.0004036036,0.00009704255,0.00008905499,0.0002168301,0.00002503973],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006232885,"about_ca_system_score_gemma":0.0001254884,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002384879,"about_ca_topic_score_gemma":0.000003403409,"domain_scores_codex":[0.997813,0.00003660084,0.0008990573,0.0004072382,0.0004761708,0.0003678634],"domain_scores_gemma":[0.9980033,0.0004451927,0.0004669283,0.0008609818,0.0001254745,0.00009810729],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000096351,0.0001840442,0.001161789,0.0008434585,0.0001644591,0.0000105473,0.0003798241,0.00004156014,0.9664142,0.00006176191,0.0000275334,0.03061446],"study_design_scores_gemma":[0.0003398547,0.00003249954,0.0006135798,0.0004478051,0.0001354274,0.00005478886,0.0007367343,0.00002364923,0.9962671,0.0004320796,0.0006465878,0.000269936],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9653099,0.0008067705,0.00002446772,0.0001776128,0.00003399286,0.00006702393,0.0001204097,0.00006853612,0.03339125],"genre_scores_gemma":[0.9965299,0.0002570531,0.0008630572,0.00001552578,0.00007682962,0.0000116176,0.00001055943,0.00005996167,0.002175441],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03122002,"threshold_uncertainty_score":0.9999332,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006088109534287203,"score_gpt":0.2302333430140822,"score_spread":0.224145233479795,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}