{"id":"W2952054178","doi":"10.1002/chin.201526038","title":"ChemInform Abstract: Hydrogenations at Room Temperature and Atmospheric Pressure with Mesoionic Carbene‐Stabilized Borenium Catalysts.","year":2015,"lang":"en","type":"article","venue":"ChemInform","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Mesoionic; Chemistry; Carbene; Boranes; Catalysis; Base (topology); Atmospheric pressure; Borane; Organic chemistry; Photochemistry; Boron","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001826301,0.0004951764,0.0001963752,0.0003004567,0.0002858955,0.0002928402,0.000801501,0.0002700329,0.006526886],"category_scores_gemma":[0.0001605509,0.0001704225,0.0001155606,0.0002934151,0.0002237824,0.000459242,0.0004160306,0.0005168102,0.001558965],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004419829,"about_ca_system_score_gemma":0.0003270152,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007800504,"about_ca_topic_score_gemma":0.001250649,"domain_scores_codex":[0.9998599,0.00001322258,0.000006579613,0.00002395438,0.00005088966,0.0000454426],"domain_scores_gemma":[0.9999636,0.000004423952,0.000009248436,0.000006655207,0.000006146884,0.000009821006],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008264249,0.000103681,0.0003737988,0.0004912659,0.00005635935,0.0002709173,0.0001609926,0.0004896109,0.9539197,0.00799283,0.01531708,0.01999733],"study_design_scores_gemma":[0.0001324111,0.0002153619,0.000835016,0.0000187357,0.00002272817,0.0002616407,0.00003158837,0.0008721133,0.9655787,0.0003316749,0.03168272,0.00001737794],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8047189,0.007922186,0.01453772,0.001241177,0.000680402,0.000253566,0.005803127,0.003058949,0.161784],"genre_scores_gemma":[0.9829298,0.002201992,0.002676456,0.0001113181,0.00004273405,0.00004080664,0.00287132,0.0001397331,0.008985857],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006526886,"threshold_uncertainty_score":0.02183461,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007521270707474709,"score_gpt":0.208722941691558,"score_spread":0.2012016709840833,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}