{"id":"W2952096981","doi":"10.1021/ol061374l","title":"Synthesis of 2-Vinylic Indoles and Derivatives via a Pd-Catalyzed Tandem Coupling Reaction","year":2006,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":179,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Curtin University of Technology","keywords":"Chemistry; Tandem; Catalysis; Combinatorial chemistry; Cascade reaction; Coupling reaction; Reaction conditions; Heck reaction; Palladium; Coupling (piping); Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001705128,0.0004823525,0.0003687938,0.0002831398,0.000249316,0.0003454814,0.0006206133,0.0002939647,0.001908162],"category_scores_gemma":[0.0001228856,0.0002436091,0.0002872159,0.0003082587,0.000146417,0.0002905598,0.000300435,0.0004645951,0.0009271901],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003938426,"about_ca_system_score_gemma":0.0003596818,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007599751,"about_ca_topic_score_gemma":0.001705124,"domain_scores_codex":[0.9998326,0.00001732812,0.00001374676,0.00004035853,0.00004310112,0.00005274709],"domain_scores_gemma":[0.9999434,0.000004050651,0.00001407166,0.000006826238,0.000007942543,0.00002367888],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001261466,0.00006651165,0.0001232414,0.0002031264,0.00002784245,0.0005121847,0.00008225633,0.001045899,0.9746855,0.001289244,0.0005042558,0.02133386],"study_design_scores_gemma":[0.00005235932,0.0008406275,0.000853172,0.00001742574,0.0000441567,0.001196604,0.00002881413,0.001534217,0.9726161,0.000212276,0.02256263,0.00004152247],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8974134,0.01249096,0.04817253,0.0002437455,0.0002986711,0.0003104601,0.001016026,0.001342974,0.03871116],"genre_scores_gemma":[0.9622529,0.003697379,0.02330131,0.00009000663,0.00003224975,0.00009343494,0.0004941643,0.00006552626,0.00997307],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001908162,"threshold_uncertainty_score":0.006383419,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007148222427239769,"score_gpt":0.2164778292870765,"score_spread":0.2093296068598368,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}