{"id":"W2952162282","doi":"10.1055/s-2000-7153","title":"Combined Directed<i>ortho</i>Metalation - Grubbs Metathesis Tactics. Synthesis of Benzazepine, Benzazocine, and Benzannulated 7-, 8-, 9-, and 15-Membered Ring Sulfonamide Heterocycles","year":2000,"lang":"en","type":"article","venue":"Synlett","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Benzazepine; Chemistry; Metathesis; Metalation; Ring (chemistry); Salt metathesis reaction; Stereochemistry; Sulfonamide; Ring-closing metathesis; Combinatorial chemistry; Closure (psychology); Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002208054,0.000547764,0.000293865,0.0002575051,0.0002009361,0.0002265707,0.0004934947,0.0001906891,0.001322603],"category_scores_gemma":[0.0001436029,0.0002197869,0.0002328553,0.0001855598,0.0002308749,0.0002546546,0.0003354577,0.0004428329,0.0006446983],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003851145,"about_ca_system_score_gemma":0.0003826089,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000566816,"about_ca_topic_score_gemma":0.002097493,"domain_scores_codex":[0.9998184,0.00003013932,0.00001550197,0.00003671012,0.0000431746,0.000056189],"domain_scores_gemma":[0.9999547,0.000004869075,0.00001692379,0.000008320467,0.000005868506,0.000009345251],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002428987,0.00009561762,0.0003056352,0.0002559675,0.00003323172,0.000468168,0.0001581775,0.0009438634,0.9656041,0.005964359,0.001024147,0.02490379],"study_design_scores_gemma":[0.00006772109,0.0007317129,0.0008816544,0.00001234915,0.0000327088,0.0006697778,0.00002520028,0.001005872,0.98603,0.0004925177,0.01002839,0.00002211962],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8770834,0.005333764,0.06375696,0.0004559198,0.0003944126,0.0005135013,0.0009775286,0.001312422,0.05017214],"genre_scores_gemma":[0.978973,0.002006533,0.01319629,0.0001065941,0.00002628414,0.0001059307,0.0003176336,0.00005565977,0.005212024],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001322603,"threshold_uncertainty_score":0.004424512,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009266410463438676,"score_gpt":0.2323690487754187,"score_spread":0.22310263831198,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}