{"id":"W2952183520","doi":"10.1002/chin.200649246","title":"Blue, but Not a Mirage: Stable Aminoketenes by Carbene Carbonylation","year":2006,"lang":"en","type":"article","venue":"ChemInform","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Carbene; Carbonylation; Organic chemistry; Astrobiology; Catalysis; Carbon monoxide","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002746594,0.0004987943,0.0003243026,0.0003033078,0.000477901,0.0005519102,0.0005343902,0.000538821,0.007420318],"category_scores_gemma":[0.0004144109,0.0002519769,0.0002025222,0.0002351692,0.0005358661,0.001308128,0.0006600164,0.001445896,0.002088614],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003513271,"about_ca_system_score_gemma":0.0002008227,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000644171,"about_ca_topic_score_gemma":0.001239181,"domain_scores_codex":[0.9997748,0.00002204611,0.000006425276,0.00005639237,0.00005718752,0.00008318315],"domain_scores_gemma":[0.9998928,0.00002517994,0.00001523726,0.0000177222,0.00001301233,0.00003602553],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007418699,0.0002926432,0.0002922807,0.0007575647,0.00007419643,0.0009478567,0.0005822687,0.001258043,0.8934621,0.03017881,0.03237726,0.03903518],"study_design_scores_gemma":[0.0001632163,0.001384876,0.000841225,0.00006392788,0.00003672183,0.0006609327,0.0001282985,0.002744253,0.9187829,0.005197364,0.06991066,0.00008563213],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7254557,0.01474404,0.03408435,0.004183311,0.004438594,0.0002838048,0.001143206,0.002241988,0.2134251],"genre_scores_gemma":[0.9599699,0.003993686,0.003124307,0.0005691208,0.0001228755,0.00005403683,0.0002485564,0.0002797744,0.03163766],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007420318,"threshold_uncertainty_score":0.02482349,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005735801136960161,"score_gpt":0.1994257027127783,"score_spread":0.1936899015758182,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}