{"id":"W2952201012","doi":"10.1002/chin.201118030","title":"ChemInform Abstract: Intramolecular Regioselective Addition of Radicals and Carbanions to Ynol Ethers. A Strategy for the Synthesis of Exocyclic Enol Ethers.","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Trois-Rivières","funders":"","keywords":"Chemistry; Regioselectivity; Carbanion; Enol; Intramolecular force; Radical; Enol ether; Organic chemistry; Medicinal chemistry; Stereochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002006283,0.0002704925,0.0004180554,0.0000694205,0.0000900189,0.00001682509,0.0004177106,0.0003628252,0.001440032],"category_scores_gemma":[0.001464859,0.0002163797,0.0002258525,0.0002231891,0.0004564365,0.0001482377,0.00006468428,0.0003420892,0.000005814372],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000133203,"about_ca_system_score_gemma":0.0001283699,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002510373,"about_ca_topic_score_gemma":0.00001080176,"domain_scores_codex":[0.9983937,2.703131e-7,0.0006266254,0.0002898583,0.0003066028,0.0003829588],"domain_scores_gemma":[0.997516,0.001138551,0.0003749044,0.0005453027,0.0001773528,0.0002478857],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000348402,0.0002358758,0.000008549228,0.0005580292,0.0004564952,0.000002116373,0.003040454,0.00000169195,0.6358761,0.001017009,0.007627606,0.3508277],"study_design_scores_gemma":[0.0003644358,0.0000556181,0.0001663817,0.0001617508,0.0001587062,0.00001427998,0.00165,0.00003730242,0.9900085,0.0008274217,0.006324891,0.0002306719],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.1195745,0.0002540612,0.00002164785,0.0002240288,0.00004100109,0.001035387,0.0004162298,0.00009962191,0.8783335],"genre_scores_gemma":[0.9983044,0.00007727502,0.0001339649,0.00007534359,0.00006546231,0.0006344302,0.0000326882,0.00004026368,0.0006361447],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.8787299,"threshold_uncertainty_score":0.9994728,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03079947595715976,"score_gpt":0.2600743216502779,"score_spread":0.2292748456931182,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}