{"id":"W2952202938","doi":"10.1002/chin.200501083","title":"Heck Reactions of Aryl Halides in Phosphonium Salt Ionic Liquids: Library Screening and Applications.","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Phosphonium; Aryl; Phosphonium salt; Halide; Salt (chemistry); Ionic bonding; Organic chemistry; Ionic liquid; Heck reaction; Combinatorial chemistry; Catalysis; Ion; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006699103,0.0001526217,0.0001952651,0.00009213646,0.00009345194,0.0000538281,0.0001669509,0.0001472307,0.0002062882],"category_scores_gemma":[0.00005549909,0.0001705506,0.00007318082,0.0003138311,0.0001756074,0.000455238,0.0001054528,0.0002645162,0.00001909519],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001091612,"about_ca_system_score_gemma":0.0001472152,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003069255,"about_ca_topic_score_gemma":0.00002197591,"domain_scores_codex":[0.9989715,1.095923e-8,0.0004385033,0.0002295364,0.0001374208,0.000223037],"domain_scores_gemma":[0.9991805,0.00009659643,0.000167526,0.0004257041,0.00003490967,0.0000947419],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001570275,0.0004860134,0.005529768,0.001288816,0.000115432,0.00001064733,0.001468034,0.000381687,0.91012,0.005426076,0.001102927,0.07391363],"study_design_scores_gemma":[0.0006465819,0.000007014632,0.000728816,0.0001972068,0.00001785881,0.00005007494,0.0005249121,0.00004062881,0.9841896,0.0007398996,0.01268644,0.0001709726],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9416746,0.0008576387,0.00004746264,0.0003224502,0.00003819169,0.0001881502,0.00006230268,0.0002379456,0.05657127],"genre_scores_gemma":[0.9961992,0.0002830164,0.0002096855,0.0000329165,0.00009490205,0.0001122124,0.0001815294,0.00003056268,0.00285601],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07406966,"threshold_uncertainty_score":0.6954854,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009743676533460286,"score_gpt":0.2398504463644158,"score_spread":0.2301067698309555,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}