{"id":"W2952202938","doi":"10.1002/chin.200501083","title":"Heck Reactions of Aryl Halides in Phosphonium Salt Ionic Liquids: Library Screening and Applications.","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Phosphonium; Aryl; Phosphonium salt; Halide; Salt (chemistry); Ionic bonding; Organic chemistry; Ionic liquid; Heck reaction; Combinatorial chemistry; Catalysis; Ion; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006429784,0.0007536357,0.0005664479,0.0008592567,0.0003542798,0.0005389528,0.0007286949,0.0004573565,0.005405887],"category_scores_gemma":[0.0007563395,0.0004239229,0.0004073197,0.001047093,0.0002866097,0.0007985256,0.0005664501,0.0006268636,0.002489008],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004277528,"about_ca_system_score_gemma":0.0003574995,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007243714,"about_ca_topic_score_gemma":0.002205418,"domain_scores_codex":[0.9997455,0.00006321831,0.00001606265,0.00004089419,0.00006604914,0.0000682717],"domain_scores_gemma":[0.999835,0.00006249108,0.00002508822,0.00002499075,0.00002997917,0.00002246384],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008642604,0.0002972905,0.0005594349,0.0007741745,0.00009905615,0.0003673236,0.0001808026,0.001400589,0.9261341,0.001313409,0.00174813,0.06626147],"study_design_scores_gemma":[0.00002969256,0.0004271708,0.0002808377,0.0000166598,0.00006417117,0.000158925,0.00003362943,0.0004619459,0.9928408,0.00009581559,0.005575129,0.00001523911],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8333687,0.04147732,0.06428985,0.0007644412,0.0001978792,0.0009745773,0.002644448,0.001953296,0.0543296],"genre_scores_gemma":[0.9130639,0.03227225,0.02646463,0.0002262684,0.00006963614,0.0003404018,0.001690448,0.0001612048,0.02571109],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005405887,"threshold_uncertainty_score":0.01808447,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009743676533460286,"score_gpt":0.2398504463644158,"score_spread":0.2301067698309555,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}